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27
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33750595439
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Originally, the product of this reaction was formulated as an allenylidene species, see: K. J. Harlow, A. F. Hill, J. D. E. T. Wilton-Ely, J. Chem. Soc. Dalton Trans. 1999, 285-291.
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Harlow, K.J.1
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Wilton-Ely, J.D.E.T.3
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28
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4344688918
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note
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31P NMR showed no peak for free phosphine during the transformation indicating that dissociation/association of phosphine is too fast for detection by NMR spectroscopy.
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29
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4344653949
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note
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Formation of a black precipitate, probably containing metallic ruthenium, was observed when heating the solution for more than 2 hours.
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