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41
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25144482388
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note
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Owing to the low binding strength of the alkene ligand to ruthenium, alkene reorientation may proceed either by alkene dissociation and re-association or by intramolecular alkene ligand rotation. Since the active alkene conformation is more stable than the inactive conformation anyway, alkene rotation should be irrelevant in the catalytic cycle.
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44
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note
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-1.
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