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Compare to: (a) Bodner, G. M.; Kahl, S. B.: Bork, K.: Starhoff, B. N.; Wuller, J. E.; Todd, L. J. Inorg. Chem. 1973, 12, 1071-1074.
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Todd, L.6
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63
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85087251146
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note
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6e solvent mixture in 3 h.
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65
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5344228485
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Nguyen, S.T.1
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0003831080
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See also: (a) Szwarc, M. Carbanions, Living Polymers and Electron Transfer Processes, Wiley-Interscience: New York. 1968. (b) van Beylen, M.; Bywater, S.; Smets, G.; Szwarc, M., Worsfold, D. J. Adv. Polym. Sci. 1988, 86, 87-143. (c) Quirk, R P.; Lee, B. Polym. Int. 1992, 27, 359-367. (d) Webster, O. W. Science 1991, 251, 887-893.
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Szwarc, M.1
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67
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See also: (a) Szwarc, M. Carbanions, Living Polymers and Electron Transfer Processes, Wiley-Interscience: New York. 1968. (b) van Beylen, M.; Bywater, S.; Smets, G.; Szwarc, M., Worsfold, D. J. Adv. Polym. Sci. 1988, 86, 87-143. (c) Quirk, R P.; Lee, B. Polym. Int. 1992, 27, 359-367. (d) Webster, O. W. Science 1991, 251, 887-893.
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Van Beylen, M.1
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68
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0026642804
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See also: (a) Szwarc, M. Carbanions, Living Polymers and Electron Transfer Processes, Wiley-Interscience: New York. 1968. (b) van Beylen, M.; Bywater, S.; Smets, G.; Szwarc, M., Worsfold, D. J. Adv. Polym. Sci. 1988, 86, 87-143. (c) Quirk, R P.; Lee, B. Polym. Int. 1992, 27, 359-367. (d) Webster, O. W. Science 1991, 251, 887-893.
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See also: (a) Szwarc, M. Carbanions, Living Polymers and Electron Transfer Processes, Wiley-Interscience: New York. 1968. (b) van Beylen, M.; Bywater, S.; Smets, G.; Szwarc, M., Worsfold, D. J. Adv. Polym. Sci. 1988, 86, 87-143. (c) Quirk, R P.; Lee, B. Polym. Int. 1992, 27, 359-367. (d) Webster, O. W. Science 1991, 251, 887-893.
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73
-
-
85087251193
-
-
note
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2 (3), supposedly due to backbiting and chain transfer as side reactions.
-
-
-
-
75
-
-
85087250894
-
-
note
-
2 (B) does not react with cyclooctatetraene.
-
-
-
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76
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0002728120
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Schumpf, A. W.; Saive, E.; Demonceau, A.; Noels, A F. J Chem. Soc., Chem. Commun. 1995, 1127-1128.
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Noels, A.F.4
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78
-
-
85087250446
-
-
note
-
2 (R = Me and Et) after 1 day.
-
-
-
-
79
-
-
0012359454
-
-
Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands
-
For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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33847801002
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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Schrock, R.R.1
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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0001606521
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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For examples of methylidene complexes, see: (a) Brookhart, M.; Liu. Y. In Advances in Metal Carbene Chemistry; Schubert, U., Ed.; Kluwer Academic: Dordrecht, The Netherlands, 1989; Vol. 269, p 251. (b) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577-6578. (c) Schrock, R. R. Acc Chem Res. 1979, 12, 98-104. (d) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc 1966, 88, 5044-5045. (e) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408-414. (f) Bodnar, T. W.; Cutler, A. R. J. Am. Chem, Soc. 1983, 105,5926-5928. (g) Bodnar, T. W.; Cutler, A. R. Organometallics 1985, 4, 1558-1565. (h) Brookhart, M.; Nelson, G. O. J. Am. Chem. Soc. 1977, 99, 6099-6101. (i) Brookhart, M.; Tucker, J. R.; Flood, T. C.; Jensen, J. J. Am. Chem. Soc. 1980, 101, 1203-1205. (J) Guerchais, V.; Astruc, D. J. Chem. Soc., Chem. Commun. 1985, 835-837. (k) Keeley, S. E.; Brookhart, M.; Husk, G. R. Organometallics 1982, 1, 760-762. (l) Klein, D. P.; Bergman, R. G. J. Am. Chem Soc. 1989, 11, 3079-3080. (m) Holmes, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1981, 103, 4599-4600. (n) Hill, A. F.; Roper, W. R.; Waters, J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939-5940.
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95
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85087249224
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note
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n = 59.7 kg/mol; PDI(toluene) = 1.42.
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96
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85087248018
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note
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2 at room temperature in 15 nun to give 4,4-diethylcyclopentene dicarboxylate quantitatively.
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97
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84899891187
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There is abundant evidence that the key step in olefin metathesis consists of the reaction between a transition metal-carbon double bond (M=CHR) and an olefin to give a metallacyclobutane ring, which was first proposed by: Hemson, J. L.; Chauvin, Y. Makromol. Chem. 1970. 141, 161.
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Chauvin, Y.2
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100
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84909761865
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was slightly altered
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3, described by Issleib and Brack (Issleib, K.; Brack, A. Z. Anorg. Allg. Chem. 1954, 277, 258-270), was slightly altered.
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Issleib, K.1
Brack, A.Z.2
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101
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5344255871
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Experimental Organomeiailic Chemistry: A Practiciun in Synthesis and Characterization; Wayda, A. L., Darensbourg, M. Y., Eds., American Chemical Society: Washington. DC
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The crystal was immersed in a lube-oil additive, which allows for manipulation on the bench-top and prevents decomposition due to air or moisture. The crystal was secured to a glass fiber (the oil acts as the adhesive) which is attached to an elongated brass mounting pin. Further details were described by: Hope, H. In Experimental Organomeiailic Chemistry: A Practiciun in Synthesis and Characterization; ACS Symp. Ser. No. 357; Wayda, A. L., Darensbourg, M. Y., Eds., American Chemical Society: Washington. DC, 1987.
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