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Volumn 119, Issue 44, 1997, Pages 10743-10753

Oxidation-state-dependent reactivity and catalytic properties of a Rh(I) complex formed from a redox-switchable hemilabile ligand

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; METAL COMPLEX; RHODIUM COMPLEX;

EID: 0030771665     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9723601     Document Type: Article
Times cited : (77)

References (70)
  • 14
    • 1542639278 scopus 로고
    • (h) Noyori, R. Science 1990, 248, 1194.
    • (1990) Science , vol.248 , pp. 1194
    • Noyori, R.1
  • 40
    • 16944365562 scopus 로고
    • Webb, G. A., Ed.; The Chemical Society: London
    • (a) Sharp, R. R. In Nuclear Magnetic Resonance: Webb, G. A., Ed.; The Chemical Society: London, 1994; Vol. 24, p 469.
    • (1994) Nuclear Magnetic Resonance , vol.24 , pp. 469
    • Sharp, R.R.1
  • 43
    • 16944363588 scopus 로고    scopus 로고
    • note
    • +, a subsequent fast electron transfer step most likely occurs after the rate determining step. Since this fast step is thermodynamically favorable, the values for k, ΔG‡, ΔH‡, and ΔS‡ are a measure for the step in which the ferrocenyl arene is displaced from the Rh(I) center.
  • 49
    • 16944367506 scopus 로고    scopus 로고
    • note
    • + interfere with the accurate integration of both the substrate and product resonances.
  • 54


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.