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Volumn 252, Issue 21-22, 2008, Pages 2314-2345

NMR spectroscopy in coordination supramolecular chemistry: A unique and powerful methodology

Author keywords

Host guest systems; Molecular recognition; NMR spectroscopy; Self assembly; Structure elucidation; Supramolecular chemistry

Indexed keywords


EID: 52949112258     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ccr.2008.01.025     Document Type: Review
Times cited : (152)

References (287)
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    • J. Jeener, Ampère International Summer School Basko Polje, Yugoslavia (1971).
    • J. Jeener, Ampère International Summer School Basko Polje, Yugoslavia (1971).
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    • Ref. [80] (Chapter 5).
    • Ref. [80] (Chapter 5).
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    • 15N correlations.
    • 15N correlations.
  • 148
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    • The Nuclear Overhauser Effect (NOE) is the change in intensity of a resonance when the spin transitions of another are somehow perturbed from their equilibrium populations. See ref. [80] (Chapter 8).
    • The Nuclear Overhauser Effect (NOE) is the change in intensity of a resonance when the spin transitions of another are somehow perturbed from their equilibrium populations. See ref. [80] (Chapter 8).
  • 149
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    • c is the correlation time, a parameter inversely proportional to the speed of the tumbling motion of the molecule. Thus, changes in the spectrometer, the temperature and the solvent can strongly influence the NOE.
    • c is the correlation time, a parameter inversely proportional to the speed of the tumbling motion of the molecule. Thus, changes in the spectrometer, the temperature and the solvent can strongly influence the NOE.
  • 150
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    • ROEs develop while the magnetisation is held static in the transverse plane, rather than along the longitudinal axis, as NOEs.
    • ROEs develop while the magnetisation is held static in the transverse plane, rather than along the longitudinal axis, as NOEs.
  • 151
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    • Ref. [80] (Chapter 8).
    • Ref. [80] (Chapter 8).
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    • The ROESY experiment is also termed CAMELSPIN (Cross-relaxation Appropiate for Minimolecules Emulated by Locked SPINs), as the cross-relaxation takes place in the rotating frame with spin-locked magnetization.
    • The ROESY experiment is also termed CAMELSPIN (Cross-relaxation Appropiate for Minimolecules Emulated by Locked SPINs), as the cross-relaxation takes place in the rotating frame with spin-locked magnetization.
  • 162
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    • AB is relatively insensitive to the experimental accuracy (a factor of 2 error in the growth rate leads to only ca. 10% error in the distance).
    • AB is relatively insensitive to the experimental accuracy (a factor of 2 error in the growth rate leads to only ca. 10% error in the distance).
  • 165
    • 52949089199 scopus 로고    scopus 로고
    • This guest dissociation is slower than the rate of C-H bond activation, indicating that the reactions with the encapsulated guest occur within the cavity of the host.
    • This guest dissociation is slower than the rate of C-H bond activation, indicating that the reactions with the encapsulated guest occur within the cavity of the host.
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    • 52949152102 scopus 로고    scopus 로고
    • 1, to avoid saturation effects.
    • 1, to avoid saturation effects.
  • 212
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    • solvent = ca. 2 the substitution of 6 by 4, or its multiplication by an empirical factor f (f < 1) have been proposed. See for instance.
    • solvent = ca. 2 the substitution of 6 by 4, or its multiplication by an empirical factor f (f < 1) have been proposed. See for instance.
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    • monomer)
    • monomer)
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    • 3 diffuse together with the cation, as confirmed by NOE and PGSE measurements.
    • 3 diffuse together with the cation, as confirmed by NOE and PGSE measurements.
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    • o.
    • o.
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    • Some of the most frequently used programs are DNMR (D.S. Stephenson, G. Binsch, J. Magn. Reson. 32 (1978) 145); gNMR (http://home.cc.umanitoba.ca/∼budzelaa/gNMR/gNMR.html); MEX/MEXICO (http://www.chemistry.mcmaster.ca/bain/exchange.html and A.D. Bain, G.J. Duns, Can. J. Chem. 74 (1996) 819), and WIN-DYNAMICS (by Bruker).
    • Some of the most frequently used programs are DNMR (D.S. Stephenson, G. Binsch, J. Magn. Reson. 32 (1978) 145); gNMR (http://home.cc.umanitoba.ca/∼budzelaa/gNMR/gNMR.html); MEX/MEXICO (http://www.chemistry.mcmaster.ca/bain/exchange.html and A.D. Bain, G.J. Duns, Can. J. Chem. 74 (1996) 819), and WIN-DYNAMICS (by Bruker).
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    • http://www.chemistry.mcmaster.ca/bain/cifman.pdf.
    • http://www.chemistry.mcmaster.ca/bain/cifman.pdf.
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    • Ref. [80] (Section 8.7.4).
    • Ref. [80] (Section 8.7.4).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.