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The Nuclear Overhauser Effect (NOE) is the change in intensity of a resonance when the spin transitions of another are somehow perturbed from their equilibrium populations. See ref. [80] (Chapter 8).
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c is the correlation time, a parameter inversely proportional to the speed of the tumbling motion of the molecule. Thus, changes in the spectrometer, the temperature and the solvent can strongly influence the NOE.
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c is the correlation time, a parameter inversely proportional to the speed of the tumbling motion of the molecule. Thus, changes in the spectrometer, the temperature and the solvent can strongly influence the NOE.
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ROEs develop while the magnetisation is held static in the transverse plane, rather than along the longitudinal axis, as NOEs.
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ROEs develop while the magnetisation is held static in the transverse plane, rather than along the longitudinal axis, as NOEs.
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The ROESY experiment is also termed CAMELSPIN (Cross-relaxation Appropiate for Minimolecules Emulated by Locked SPINs), as the cross-relaxation takes place in the rotating frame with spin-locked magnetization.
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The ROESY experiment is also termed CAMELSPIN (Cross-relaxation Appropiate for Minimolecules Emulated by Locked SPINs), as the cross-relaxation takes place in the rotating frame with spin-locked magnetization.
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AB is relatively insensitive to the experimental accuracy (a factor of 2 error in the growth rate leads to only ca. 10% error in the distance).
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AB is relatively insensitive to the experimental accuracy (a factor of 2 error in the growth rate leads to only ca. 10% error in the distance).
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This guest dissociation is slower than the rate of C-H bond activation, indicating that the reactions with the encapsulated guest occur within the cavity of the host.
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Some of the most frequently used programs are DNMR (D.S. Stephenson, G. Binsch, J. Magn. Reson. 32 (1978) 145); gNMR (http://home.cc.umanitoba.ca/∼budzelaa/gNMR/gNMR.html); MEX/MEXICO (http://www.chemistry.mcmaster.ca/bain/exchange.html and A.D. Bain, G.J. Duns, Can. J. Chem. 74 (1996) 819), and WIN-DYNAMICS (by Bruker).
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Some of the most frequently used programs are DNMR (D.S. Stephenson, G. Binsch, J. Magn. Reson. 32 (1978) 145); gNMR (http://home.cc.umanitoba.ca/∼budzelaa/gNMR/gNMR.html); MEX/MEXICO (http://www.chemistry.mcmaster.ca/bain/exchange.html and A.D. Bain, G.J. Duns, Can. J. Chem. 74 (1996) 819), and WIN-DYNAMICS (by Bruker).
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http://www.chemistry.mcmaster.ca/bain/cifman.pdf.
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Ref. [80] (Section 8.7.4).
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Ref. [80] (Section 8.7.4).
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