Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: Structures and mechanism of formation

Angewandte Chemie - International Edition

Volumn 41, Issue 18, 2002, Pages 3371-3375

  Su, Cheng Yong ^a   Cai, Yue Peng ^a   Chen, Chun Long ^a   Lissner, Falk ^b   Kang, Bei Sheng ^a   Kaim, Wolfgang ^b  

^a SUN YAT SEN UNIVERSITY   (China)

^b UNIVERSITY OF STUTTGART   (Germany)

Author keywords

Cage compounds; Copper; Host guest systems; Self assembly; Solid state structures

Indexed keywords

ENCAPSULATION; NEGATIVE IONS; STRUCTURE (COMPOSITION); THERMODYNAMIC STABILITY;

METALLOCAGES;

SELF ASSEMBLY;

ANION; BORON DERIVATIVE; COPPER DERIVATIVE; FLUORINE DERIVATIVE; IODINE DERIVATIVE; METAL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLIZATION; MOLECULAR STABILITY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0037119775     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20020916)41:18<3371::AID-ANIE3371>3.0.CO;2-4     Document Type: Article

References (57)

1. a) L. M. Greig, D. Philp, Chem. Soc. Rev. 2001, 30, 287;
2. b) A. R. Navarro, B. Lippert, Coord. Chem. Rev. 2001, 222, 219;
3. c) B. Cinton, A. D. Hamilton, Chem. Rev. 1997, 97, 5;
4. d) G. F. Swieger, T. J. Malefetse, Chem. Rev. 2000, 100, 3483;
5. e) C. J. Jones, Chem. Soc. Rev. 1998, 27, 289.
6. a) S. Leininger, B. Olenyuk, P. J. Stang, Chem. Rev. 2000, 100, 853;
7. b) M. Fujita, K. Umemoto, M. Yoshizawa, N. Fujita, T. Kusukawa, K. Biradha, Chem. Commu. 2001, 509;
8. c) D. L. Caulder, K. N. Raymond, Acc. Chem. Res. 1999, 32, 975;
9. d) R. W. Saalfrank, E. Uller, 13. Demleitner, I. Bernt, Struct. Bonding (Berlin) 2000, 96, 149;
10. e) B. Moulton, J. Lu, A. Mondal, M. J. Zaworotko, Chem. Commun. 2001, 863;
11. f) P. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92; Angew. Chem. Int. Ed. Engl. 1993, 32, 69;
12. f) P. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92; Angew. Chem. Int. Ed. Engl. 1993, 32, 69;
13. g) P. Jacopozzi, E. Dalcanale, Angew. Chem. 1993, 109, 665; Angew. Chem. Int. Ed. Engl. 1997, 36, 613.
14. g) P. Jacopozzi, E. Dalcanale, Angew. Chem. 1993, 109, 665; Angew. Chem. Int. Ed. Engl. 1997, 36, 613.
15. N. Takeda, K. Umemoto, K. Yamaguchi, M. Fujita, Nature 1999, 398, 794.
16. a) B. F. Abrahams, S. J. Egan, R. Robson, J. Am. Chem. Soc. 1999, 121, 3535;
17. b) M. Hong, Y. Zhao, W, Su, R. Cao, M. Fijita, Z. Zhou, A. S. C. Chan. J. Am. Chem. Soc. 2000, 122, 4819.
18. B. Olenyuk, M. D. Levin, J. A. Whiteford, J. E. Shield, P. J. Stang, J. Am. Chem. Soc. 1999, 121, 10434.
19. C. J. Kuehl, S. D. Huang, P. J. Stang, J. Am. Chem. Soc. 2001, 123, 9634.
20. a) M. Fujita, S. Nagao, K. Ogura, J. Am. Chem. Soc. 1995, 117, 1649;
21. b) S. Hiraoka, M. Fujita, J. Am. Chem. Soc. 1999, 121, 10239;
22. c) H. K. Liu, W. Y. Sun, D. J. Ma, K. B. Yu, W. X. Tang, Chem. Commun. 2000, 591;
23. d) U. Radhakrishnan, M. Schweiger, P. J. Stang, Org. Lett. 2001, 3, 3141;
24. e) P. M. VanCalcar, M. M. Olmstead, A. L. Balch, Chem. Commun. 1996, 2597.
25. C. Piguet, G. Bernardinelli, G. Hopfgartner, Chem. Rev. 1997, 97, 2005; M. Albrecht, Chem. Rev. 2001, 101, 5457.
26. C. Piguet, G. Bernardinelli, G. Hopfgartner, Chem. Rev. 1997, 97, 2005; M. Albrecht, Chem. Rev. 2001, 101, 5457.
27. a) M. D. Levin. P. J. Stang, J. Am. Chem. Soc. 2000, 122, 7428;
28. b) D. W. Johnson, K. N. Raymond, Inorg. Chem. 2001, 40, 5157.
29. a) C.-Y. Su, X.-P. Yang, B.-S. Kang, T. C. W. Mak, Angew. Chem. 2001, 113, 1775; Angew. Chem. Int. Ed. 2001, 40, 1725;
30. a) C.-Y. Su, X.-P. Yang, B.-S. Kang, T. C. W. Mak, Angew. Chem. 2001, 113, 1775; Angew. Chem. Int. Ed. 2001, 40, 1725;
31. b) C.-Y. Su, B.-S. Kang, C.-X. Du, Q.-C. Yang, T. C. W. Mak, Inorg. Chem. 2000, 39, 4843;
32. c) C.-Y. Su, B.-S. Kang, Q.-C. Wang, T. C. W. Mak, J. Chem. Soc. Dalton Trans. 2000, 1831;
33. d) C.-Y. Su, B.-S. Kang. H.-Q. Liu, Q.-C. Wang, T. C. W. Mak, Chem. Commun. 1998, 1551;
34. e) Y.-P. Cai, B.-S. Kang, C.-Y. Su, H.-X. Zhang, X.-P. Yang, L.-R. Deng, A.-W. Xu, Z.-Y. Zhou, A. Albert, S. C. Chan. Chin. J. Struct. Chem. 2001, 20, 201.
35. a) M. Fujita, D. Oguro, M. Miyazawa, H. Oka, K. Yamaguchi, K. Ogura, Nature 1995, 378, 469;
36. b) C. M. Hartshorn, P. J. Steel, Chem. Commun. 1997, 541;
37. c) P. J. Stang, B. Olenyuk, D. C. Muddiman, T. D. Smith, Organometallics 1997, 16, 3094.
38. M. Fujita, S.-Y. Yu, T. Kusukawa, H. Funaki, K. Ogura, K. Yamaguchi, Angew. Chem. 1998, 110, 2192; Angew. Chem. Int. Ed. 1998, 37, 2082.
39. M. Fujita, S.-Y. Yu, T. Kusukawa, H. Funaki, K. Ogura, K. Yamaguchi, Angew. Chem. 1998, 110, 2192; Angew. Chem. Int. Ed. 1998, 37, 2082.
40. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998, 37, 1461.
41. S. R. Batten, R. Robson, Angew. Chem. 1998, 110, 1558; Angew. Chem. Int. Ed. 1998, 37, 1461.
42. 3), 2.27 ppm (s, 36H; Me).
43. a) J. A. Whiteford, C. V. Lu, P. J. Stang. J. Am. Chem. Soc. 1997, 119, 2524;
44. b) J. A. Whitefort, P. J. Stang, S. D. Huang, Inorg. Chem. 1998, 37, 5595;
45. c) A. Lützen, A. R. Renslo, C. A. Schalley, B. M. O'Leary, J. Rebek, Jr. J. Am. Chem. Soc. 1999, 121, 7455;
46. d) M. J. Hardie, C. L. Raston, J. Chem. Soc. Dalton, Trans. 2000, 2483;
47. e) T. N. Parac, M. Scherer, K. N. Raymond, Angew. Chem. 2000, 112, 1288; Angew. Chem. Int. Ed. 2000, 39, 1239.
48. e) T. N. Parac, M. Scherer, K. N. Raymond, Angew. Chem. 2000, 112, 1288; Angew. Chem. Int. Ed. 2000, 39, 1239.
49. A. Pfitzner, D. Schmitz, Z. Anorg. Allg. Chem. 1997, 623, 1555.
50. C.-Y. Su, Y.-P. Cai, C.-L. Chen. H.-X. Zhang, B.-S. Kang, J. Chem. Soc. Dalton Trans. 2001, 359.
51. a) J. Xu, T. N. Parac, K. N. Raymond, Angew. Chem. 1999, 111, 3055; Angew. Chem. Int. Ed. 1999, 38, 2878;
52. a) J. Xu, T. N. Parac, K. N. Raymond, Angew. Chem. 1999, 111, 3055; Angew. Chem. Int. Ed. 1999, 38, 2878;
53. b) A. J. Terpin, M. Ziegler, D. W. Johnson, K. N. Raymond, Angew. Chem. 2001, 113, 161; Angew. Chem. Int. Ed. 2001, 40, 157;
54. b) A. J. Terpin, M. Ziegler, D. W. Johnson, K. N. Raymond, Angew. Chem. 2001, 113, 161; Angew. Chem. Int. Ed. 2001, 40, 157;
55. c) F. Ibukur, T. Kusukawa, M. Futiga, J. Am. Chem. Soc. 1998, 120, 8561.
56. 3).
57. z axis.