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Volumn 13, Issue 1, 2007, Pages 59-68

Solid-state self-assembly of polymeric double helicates leading to linear arrays of silver(I) ions and reversible strand/double helix interconversion in solution

Author keywords

Coordination polymers; Helical structures; Hydrazones; Self assembly; Silver; Supramolecular chemistry

Indexed keywords

COMPLEXATION; MOLECULAR STRUCTURE; SELF ASSEMBLY; SILVER; SUPRAMOLECULAR CHEMISTRY; LIGANDS; TITRATION;

EID: 33845917899     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200600726     Document Type: Article
Times cited : (80)

References (88)
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    • The complex was obtained by mixing the ligand (1.17 mg, 3.38 μmol. 1 equiv) with AgBF4 (2.55 mg, 13.08 μmol, 3.9 equiv) in CD 3CN (0.4 mL, which lead to complete dissolution of the ligand and to precipitation of the most part of the complex. 1H NMR (CD 3CN, 300 MHz, after filtration: δ, 8.84 (s, 2H; H G, 8.30 (ddd. 7, 0.9, 1.7, 4.9 Hz, 2H; HA, 7.90 (s, 2H; HF, 7.84 (ddd, J, 1.9, 7.2, 8.7 Hz, 2H; HC, 7.47 (d, 7, 8.7 Hz, 2H; HD, 7.07 (ddd, 7, 0.9, 4.9, 7.2 Hz, 2H; H B, 3.65 s. 6H; HF, Crystals suitable for crystallographic determinations were obtained by diffusion of Et2O into a solution of the complex in CH3CN. Crystallographic data: C22H24Ag2B2F8N 111, C18H18N8Ag2· 2CH3CN·2BF4
    • 3. CCDC-608541 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.