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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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16
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0001360952
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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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18
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For some selected examples, see: (a) Baxter P.; Lehn, J.-M.; DeCian, A.; Fischer, J. Angew. Chem., Int. Ed. Engl. 1993, 32, 69. (b) Drain, C. M.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1994, 2313. (c) Baxter, P. N. W.; Lehn, J.-M.; Fischer, J.; Youinou, M.-T. Angew. Chem., Int. Ed. Engl. 1994, 33, 2284. (d) Baxter, P.; Sleiman, H.; Lehn, J.-M.; Rissanen, K. Angew. Chem., Int. Ed. Engl. 1997, 36, 1294. (e) Fujita, M.; Nagao, S.; Iida, M.; Ogura, K. J. Am. Chem. Soc. 1993, 115, 1574. (f) Fujita, M.; Ibukuro, F.; Yamaguchi, K.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 4145. (g) Constable, E. C.; Schofield, E. Chem. Commun. 1998, 403.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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27
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84990095630
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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For selected examples of double-stranded helicates, see: (a) Lehn, J.-M.; Rigault, A.; Siegel, J.; Harrowfield, J.; Chevrier, B.; Moras, D. Proc. Natl. Acad. Sci. U.S.A. 1987, 84, 2565. (b) Lehn, J.-M.; Rigault, A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1095. (c) Garrett, T. M.; Koert, U.; Lehn, J.-M.; Rigault, A.; Meyer, D.; Fischer, J. J. Chem. Soc., Chem. Commun. 1990, 557. (d) Koert, U.; Harding, M. M.; Lehn, J.-M. Nature 1990, 346, 339. (e) Schoentjes, B.; Lehn, J.-M. Helv. Chim. Acta 1995, 78, 1. (f) Marquis-Rigault, A.; Dupont-Gervais, A.; Van Dorsselaer, A.; Lehn, J.-M. Chem. Eur. J. 1996, 2, 1395. (g) Constable, E. C.; Drew, M. G. B.; Ward, M. D. J. Chem. Soc., Chem. Commun. 1987, 1600. (h) Constable, E. C.; Ward, M. D. J. Am. Chem. Soc. 1990, 112, 1256. (i) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruna, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422. (j) Constable, E. C.; Walker, J. V. J. Chem. Soc., Chem. Commun. 1992, 884. (k) Constable, E. C.; Heirtzler, F. R.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Chem. Commun. 1996, 933. (l) Chotalia, R.; Constable, E. C.; Neuburger, M.; Smith, D. R.; Zehnder, M. J. Chem. Soc., Dalton Trans. 1996, 4207.
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Electrospray mass spectrometry (ES-MS) was recently shown to be the more suitable technique for obtaining molecular peaks of relatively weak metallosupramolecular complexes. However, this technique is not currently available to us. For a discussion on the different MS techniques used for helcate characterization, see ref 10b, pp 2047-2050, and the references therein.
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