Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: A stepwise ion pair guest dissociation mechanism

Journal of the American Chemical Society

Volumn 128, Issue 30, 2006, Pages 9781-9797

  Leung, Dennis H ^a   Bergman, Robert G ^a   Raymond, Kenneth N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST SELECTIVITY; ENCAPSULATION; IRIDIUM; REACTION KINETICS; SUBSTRATES; SUPRAMOLECULAR CHEMISTRY; THERMODYNAMICS;

BULK SOLUTION; C-H BOND ACTIVATION; GUEST DISSOCIATION; PHOSPHINE TRAP;

HYDROGEN BONDS;

CYCLODEXTRIN; IRIDIUM; PHOSPHINE;

ARTICLE; CHEMICAL REACTION; CHIRALITY; ENTROPY; NUCLEAR OVERHAUSER EFFECT; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SUPRAMOLECULAR CHEMISTRY; TECHNIQUE; THERMODYNAMICS;

EID: 33746591182     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja061412w     Document Type: Article

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