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The signal at 3.30 ppm is very broad, but an exchange spectroscopy (EXSY) spectrum indicated a clear correlation between the peaks at 3.30 and 5.44 ppm.
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The signal at 3.30 ppm is very broad, but an exchange spectroscopy (EXSY) spectrum indicated a clear correlation between the peaks at 3.30 and 5.44 ppm.
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The circumrotation of the metallomacrocycle through the cavity of the macrocyclic polyether is fast on the 1H NMR time scale at room temperature
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