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4544289320
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note
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-3, T = 233(2) K, R = 0.0275, wR2 = 0.0512, GOF = 1.049 (I > 2.0σ(I)). CCDC-228631 (1) and CCDC-228630 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
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12
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4544363676
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note
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IV oxidation state is achieved by an air-mediated oxidation process affording the octahedral compound 1, which is very stable as denoted by the lack of any reduction wave above -1.5 V in the cyclic voltammetry experiment.
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13
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0001290133
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16
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4544350083
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note
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195Pt) and ESI-MS. All data can be found in the Supporting Information.
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17
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4544384015
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note
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1H NMR spectra.
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20
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0035188519
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22
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4544288668
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note
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STR(3): distance from the centroid formed by Pt(1)-Pt(2) to H(4) in the modeled structure of 3.
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23
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0009645995
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