What factors influence the rate constant of substrate epoxidation by compound i of cytochrome P450 and analogous iron(IV)-oxo oxidants?

Journal of the American Chemical Society

Volumn 132, Issue 22, 2010, Pages 7656-7667

  Kumar, Devesh ^a   Karamzadeh, Baharan ^b   Sastry, G Narahari ^a   De Visser, Sam P ^b  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SPECIES; ALIPHATIC HYDROXYLATION; BARRIER HEIGHTS; C-C DOUBLE BONDS; COMPOUND I; CYTOCHROME P450; CYTOCHROMES P450; DOUBLE BONDS; ELECTRON-TRANSFER; EPOXIDATION REACTIONS; FUNDAMENTAL FACTORS; HYDROXO COMPLEXES; INTRINSIC ELECTRONICS; KEY REACTIONS; NONHEME IRON; O-H BOND; OXYGENASES; POLARIZABILITIES; PORPHYRIN CATIONS; REACTION MECHANISM; SUBSTRATE HYDROXYLATION; VALENCE BONDS;

ACTIVATION ENERGY; CATALYSTS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ELECTRONIC PROPERTIES; ENZYMES; HYDROXYLATION; IONIZATION POTENTIAL; IRON COMPOUNDS; OXIDANTS; PORPHYRINS; RATE CONSTANTS; REGIOSELECTIVITY; SUBSTRATES;

EPOXIDATION;

CYTOCHROME P450; HEME; NONHEME IRON PROTEIN; OXIDIZING AGENT; PORPHYRIN DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; ENZYME ACTIVATION; ENZYME SUBSTRATE COMPLEX; EPOXIDATION; HYDROXYLATION; IONIZATION; POLARIZATION; REACTION ANALYSIS; STEREOCHEMISTRY;

CYTOCHROME P-450 ENZYME SYSTEM; HYDROXYLATION; IRON COMPOUNDS; MODELS, MOLECULAR; OXIDANTS; OXIDATION-REDUCTION; PORPHYRINS; PSEUDOMONAS PUTIDA; THERMODYNAMICS;

EID: 77953100438     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9106176     Document Type: Article

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