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Volumn 299, Issue 5609, 2003, Pages 1037-1039

Crystallographic and spectroscopic characterization of a Nonheme Fe(IV)=O complex

Author keywords

[No Author keywords available]

Indexed keywords

BIOSYNTHESIS; CATALYSIS; CRYSTALLOGRAPHY; ENZYMES; METABOLISM; OXIDATION; SPECTROSCOPY;

EID: 0037436143     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.299.5609.1037     Document Type: Article
Times cited : (809)

References (42)
  • 9
    • 0346823733 scopus 로고    scopus 로고
    • Materials and methods are available as supporting material on Science Online
    • Materials and methods are available as supporting material on Science Online.
  • 11
    • 0348084529 scopus 로고
    • A. B. P. Lever, H. B. Gray, Eds. VCH, New York
    • P. G. Debrunner, in Iron Porphyrins, A. B. P. Lever, H. B. Gray, Eds. (VCH, New York, 1989), vol. III, p. 199.
    • (1989) Iron Porphyrins , vol.3 , pp. 199
    • Debrunner, P.G.1
  • 13
    • 0348084531 scopus 로고    scopus 로고
    • note
    • The δ value of 2 is somewhat greater than those of other Fe(IV) complexes reported to date (range 0.01 to 0.14 mm/s), but our ongoing study of related Fe(IV) complexes shows that δ increases with the number of tertiary amine tigands.
  • 14
    • 0348084530 scopus 로고    scopus 로고
    • note
    • iso.
  • 15
    • 0346823731 scopus 로고    scopus 로고
    • note
    • A bis(μ-oxo)diiron(IV) complex has also been reported by Costas et al. (24) with quite distinct properties.
  • 16
    • 0346823732 scopus 로고    scopus 로고
    • note
    • 2 was reported by Che et al. (38).
  • 20
    • 0346823730 scopus 로고    scopus 로고
    • note
    • The crystal structure of an Fe(IV)(O)(porphyrin) complex with an Fe-O bond length of 1.604 Å was briefly mentioned in a footnote of Schappacher et al. (39), but this result has not been subsequently presented in greater detail.
  • 22
  • 23
    • 0034636867 scopus 로고    scopus 로고
    • C. E. MacBeth et al., Science 289, 938 (2000).
    • (2000) Science , vol.289 , pp. 938
    • MacBeth, C.E.1
  • 41
    • 0347454511 scopus 로고    scopus 로고
    • or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK
    • Copies of the data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK).
  • 42
    • 0346193150 scopus 로고    scopus 로고
    • note
    • Supported by grants from NIH (GM-33162 and GM- 38767 to L.Q. and GM-22701 to E.M.) and the Korea Science and Engineering Foundation (KOSEF) (R02-2002-000-00048-0 to W.N.), a postdoctoral fellowship from the Deutsche Forschungsgemeinschaft (J.-U.R.), and a graduate fellowship from NSF (A.S.). We also thank KOSEF and NSF for stimulating this international cooperative research effort.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.