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0348084531
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note
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The δ value of 2 is somewhat greater than those of other Fe(IV) complexes reported to date (range 0.01 to 0.14 mm/s), but our ongoing study of related Fe(IV) complexes shows that δ increases with the number of tertiary amine tigands.
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14
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0348084530
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note
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iso.
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15
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0346823731
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note
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A bis(μ-oxo)diiron(IV) complex has also been reported by Costas et al. (24) with quite distinct properties.
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16
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0346823732
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note
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2 was reported by Che et al. (38).
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0346823730
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note
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The crystal structure of an Fe(IV)(O)(porphyrin) complex with an Fe-O bond length of 1.604 Å was briefly mentioned in a footnote of Schappacher et al. (39), but this result has not been subsequently presented in greater detail.
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21
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41
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0347454511
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or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK
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Copies of the data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, UK).
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42
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0346193150
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note
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Supported by grants from NIH (GM-33162 and GM- 38767 to L.Q. and GM-22701 to E.M.) and the Korea Science and Engineering Foundation (KOSEF) (R02-2002-000-00048-0 to W.N.), a postdoctoral fellowship from the Deutsche Forschungsgemeinschaft (J.-U.R.), and a graduate fellowship from NSF (A.S.). We also thank KOSEF and NSF for stimulating this international cooperative research effort.
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