Low-temperature rapid-scan detection of reactive intermediates in epoxidation reactions catalyzed by a new enzyme mimic of cytochrome P450

Journal of the American Chemical Society

Volumn 129, Issue 41, 2007, Pages 12473-12479

  Hessenauer Ilicheva, Natalya ^a   Franke, Alicja ^a   Meyer, Dominik ^b   Woggon, Wolf D ^b   Van Eldik, Rudi ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSITY OF BASEL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; ENZYMES; EPOXIDATION; LOW TEMPERATURE EFFECTS; REACTION KINETICS;

CATALYTIC CYCLE; EPOXIDATION REACTIONS; OXYGENATION REACTIONS;

PORPHYRINS;

3 CHLOROPERBENZOIC ACID; CYTOCHROME P450; HEME; IRON DERIVATIVE; OXYGEN; PEROXIDE;

ARTICLE; BIOMIMETICS; CATALYSIS; CATALYST; CHEMICAL REACTION; COMPLEX FORMATION; ENZYME ACTIVITY; EPOXIDATION; EQUILIBRIUM CONSTANT; LOW TEMPERATURE; OXYGEN TRANSPORT; OXYGENATION; REACTION ANALYSIS; SPECTROSCOPY;

BIOMIMETIC MATERIALS; CATALYSIS; CHLOROBENZOATES; CYTOCHROME P-450 ENZYME SYSTEM; EPOXY COMPOUNDS; KINETICS; MOLECULAR STRUCTURE; SUBSTRATE SPECIFICITY; TEMPERATURE; TIME FACTORS;

EID: 35349022536     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja073266f     Document Type: Article

References (6)

1. (a) McLain, J. L.; Lee, J. J.; Groves, T. In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; Meunier, B., Ed.; Imperial College Press: London, 2000; pp 91-169.
2. (b) Meunier, B. In Metalloporphyrins Catalyzed Oxidations; Montanari, F., Casella, L., Eds.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994; pp 1-47.
3. (c) Shimada, H.; Sligar, S: G.; Yeom, H.; Ishimura, Y. In Oxygenases and Model Systems; Funabiki, T., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1997; pp 195-221.
4. (d) Watanabe, Y. In Oxygenases and Model Systems; Funabiki, T., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1997; pp 223-282.
5. (e) Traylor, T. G.; Traylor, P. S. In Active Oxygen in Biochemistry; Valentine, J. S., Foote, C. S., Greenberg, A., Liebman, J. F., Eds.; Chapman & Hall: London, 1995; pp 84-187.
6. (a) Nam, W.; Park, S.-E.; Lim, I. K.; Lim, M. H.; Hong, J.; Kim, J. J. Am. Chem. Soc. 2003, 125, 14674.