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For an edge-to-face TTF-to-xylene [S⋯π] interaction of a model host-guest complex, see: Ercolani, G.; Mencarelli, P. J. Org. Chem. 2003, 68, 6470-6473.
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For an edge-to-face TTF-to-xylene [S⋯π] interaction of a model host-guest complex, see: Ercolani, G.; Mencarelli, P. J. Org. Chem. 2003, 68, 6470-6473.
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34250869411
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6.
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6.
-
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100
-
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34250825171
-
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For another example of isomeric selectivity in the formation of [2]catenanes, refer to ref 6d
-
For another example of isomeric selectivity in the formation of [2]catenanes, refer to ref 6d.
-
-
-
-
101
-
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34250807725
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-
This assignment is further substantiated and confirmed by the relationship between the observed UV-vis-NIR absorption spectroscopic data and the cis/trans isomer ratio of the [2]catenane as confirmed by molecular modeling
-
This assignment is further substantiated and confirmed by the relationship between the observed UV-vis-NIR absorption spectroscopic data and the cis/trans isomer ratio of the [2]catenane as confirmed by molecular modeling.
-
-
-
-
102
-
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34250896648
-
-
4+ cyclophane.
-
4+ cyclophane.
-
-
-
-
103
-
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34250813559
-
-
Crystallographic data for 1·4PF6·(CD 3CN)7 at 133(2) K with Mo Kα radiation (λ, 0.71069 Å, 1·4PF6: triclinic, space group P-1, a, 13.571-(8) Å, b, 14.252(8) Å, c, 27.108(15) Å, α, 97.841(12)°, β, 91.323-(12)°, χ, 106.338(12)°, Z, 2, R1, 0.0887. wR2 all data, 0.2497, GOF, 0.810
-
6: triclinic, space group P-1, a = 13.571-(8) Å, b = 14.252(8) Å, c = 27.108(15) Å, α = 97.841(12)°, β = 91.323-(12)°, χ = 106.338(12)°, Z = 2, R1 = 0.0887. wR2 (all data) = 0.2497, GOF = 0.810.
-
-
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104
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37049074899
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Gorgues, A.1
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114
-
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34250844249
-
-
No difference in the electrochemical data collected was observed when comparing the electrochemical data of the predominately cis isomer (9:1) bismacrocycle 6 to the 1:1 isomeric cis/trans mixture of the bismacrocycle 6
-
No difference in the electrochemical data collected was observed when comparing the electrochemical data of the predominately cis isomer (9:1) bismacrocycle 6 to the 1:1 isomeric cis/trans mixture of the bismacrocycle 6.
-
-
-
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115
-
-
34250841622
-
-
No observable difference in the electrochemical data was observed when the experiments were carried out on either a 1:1 mixture of the cis and the trans isomer or the purified TTF isomers
-
No observable difference in the electrochemical data was observed when the experiments were carried out on either a 1:1 mixture of the cis and the trans isomer or the purified TTF isomers.
-
-
-
-
116
-
-
34250798960
-
-
No difference in the electrochemical data collected was observed when the [2]catenane (95:5 cis/trans) prepared from the predominately cis isomer (9:1) bismacrocycle 6 or the [2]catenane (67:33 cis/trans) prepared from a 1:1 isomeric mixture of the bismacrocycle 6 was used in individual experiments.
-
No difference in the electrochemical data collected was observed when the [2]catenane (95:5 cis/trans) prepared from the predominately cis isomer (9:1) bismacrocycle 6 or the [2]catenane (67:33 cis/trans) prepared from a 1:1 isomeric mixture of the bismacrocycle 6 was used in individual experiments.
-
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117
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34250873773
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-
For a detailed analysis of the electrochemical profile of the alongside interaction in a two-station [2]pseudorotaxane, please refer to refs 18c and 24
-
For a detailed analysis of the electrochemical profile of the alongside interaction in a two-station [2]pseudorotaxane, please refer to refs 18c and 24.
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