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6 are not shifted significantly with respect to the signals for the corresponding protons in the free macrocyclic polyethers 4 or 12. Furthermore, these protons resonate at approximately the same δ values and with the same intensities over the range of temperatures investigated. These observations suggest that the dioxybenzene unit does not reside inside the cavity of the tetracationic cyclophane in any of the [2]-catenanes.
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