The first proton-conducting metallic ion-radical salts

Angewandte Chemie - International Edition

Volumn 44, Issue 2, 2004, Pages 292-295

  Akutsu Sato, Akane ^a,e   Akutsu, Hiroki ^a,d   Turner, Scott S ^a,b   Day, Peter ^a   Probert, Michael R ^c   Howard, Judith A K ^c   Akutagawa, Tomoyuki ^f   Takeda, Sadamu ^f   Nakamura, Takayoshi ^f   Mori, Takehiko ^e  

^a DAVY FARADAY RESEARCH LABORATORY   (United Kingdom)

^b UNIVERSITY OF EXETER   (United Kingdom)

^c DURHAM UNIVERSITY   (United Kingdom)

^d UNIVERSITY OF HYOGO   (Japan)

^e TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^f HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Conducting materials; Electron transport; Ion channels; Proton transport

Indexed keywords

ELECTRIC CONDUCTIVITY; ELECTRIC CONDUCTORS; FREE RADICALS; POSITIVE IONS; PROTONS;

ION CHANNELS; METALLIC ELECTRICAL CONDUCTORS; PROTONIC CONDUCTIVITY;

SALTS;

BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE; CROWN ETHER DERIVATIVE; METAL; PROTON; RADICAL; UNCLASSIFIED DRUG; WATER;

ARTICLE; CHEMICAL STRUCTURE; CONDUCTOR; DEVICE; ELECTROCHEMICAL ANALYSIS; MATERIAL STATE; PROTON TRANSPORT; STRUCTURE ANALYSIS;

EID: 19944428857     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461686     Document Type: Article

References (17)

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11. 2 = 0,0794. Data were collected through ω-scans, at 30 K, using an Oxford Cryosystems HELIX,[3] on a Bruker SMART 1K diffractometer. A numerical absorption correction was applied using SADABS.[11] The structure was solved by direct methods and refined using full-matrix least-squares methods (SHELX97),[12] with all fully occupied atoms having position and thermal-displacement parameters refined. Hydrogen atoms were placed by Fourier and geometric methods, and refined as riding atoms. Multiple refinements were attempted to definitively determine the cations between adjacent crown ether molecules. The final model was chosen as it give the best residual Fourier map. CCDC-234609 (2) contains the supplementary Crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
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