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Volumn 4, Issue 4, 2002, Pages 557-560

Poised on the brink between a bistable complex and a compound

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ARTICLE;

EID: 0001681390     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0171362     Document Type: Article
Times cited : (49)

References (43)
  • 16
    • 0035930578 scopus 로고    scopus 로고
    • (e) Service, R. F. Science 2001, 294, 2442-2443.
    • (2001) Science , vol.294 , pp. 2442-2443
    • Service, R.F.1
  • 17
    • 37049125686 scopus 로고
    • The "slippage" methodology was first exploited for the rotaxane syntheses that were conducted in a statistical manner. For examples, see: (a) Harrison, I. T. J. Chem. Soc., Chem. Commun. 1972, 231-232.
    • (1972) J. Chem. Soc., Chem. Commun. , pp. 231-232
    • Harrison, I.T.1
  • 18
    • 33748892586 scopus 로고
    • (b) Schill, G.; Beckmann, W.; Schweikert, N.; Fritz, H.; Chem. Ber. 1986, 119, 2647-2655. The first template-directed successful synthesis of rotaxanes utilizing slippage was reported in 1993. See:
    • (1986) Chem. Ber. , vol.119 , pp. 2647-2655
    • Schill, G.1    Beckmann, W.2    Schweikert, N.3    Fritz, H.4
  • 23
    • 0002805158 scopus 로고    scopus 로고
    • Shibasaki, M., Stoddart, J. F., Vögtle, F., Eds.; VCH-Wiley: Weinheim
    • (f) Fyfe, M. C. T.; Raymo, F. M.; Stoddart, J. F. In Stimulating Concepts in Chemistry; Shibasaki, M., Stoddart, J. F., Vögtle, F., Eds.; VCH-Wiley: Weinheim, 2000; pp 211-220.
    • (2000) Stimulating Concepts in Chemistry , pp. 211-220
    • Fyfe, M.C.T.1    Raymo, F.M.2    Stoddart, J.F.3
  • 25
    • 0001675749 scopus 로고    scopus 로고
    • The distinction between rotaxanes and pseudorotaxanes is far from being a straightforward one. When size-complementarity between the stoppers and the macrocyclic component is achieved, certain "rotaxanes" behave as pseudorotaxanes and can dissociate into their constituent components under appropriate conditions. Thus, a species which is a rotaxane at ambient temperature might well be a pseudorotaxane at elevated temperatures. Even a solvent change can turn a rotaxane into a pseudorotaxane at the same temperature. See: (a) Raymo, F. M.; Stoddart, J. F. Chem. Rev. 1999, 99, 1643-1663.
    • (1999) Chem. Rev. , vol.99 , pp. 1643-1663
    • Raymo, F.M.1    Stoddart, J.F.2
  • 34
    • 0041319919 scopus 로고    scopus 로고
    • For details, see Supporting Information
    • For details, see Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.