Complexation-induced translational isomerism: Shuttling through stepwise competitive binding

Angewandte Chemie - International Edition

Volumn 45, Issue 1, 2005, Pages 77-83

  Marlin, Dana S ^a   Cabrera, Diego González ^a   Leigh, David A ^a   Slawin, Alexandra M Z ^b  

^a UNIVERSITY OF EDINBURGH   (United Kingdom)

^b UNIVERSITY OF ST ANDREWS   (United Kingdom)

Author keywords

Coordination modes; Molecular devices; Noncovalent interactions; Rotaxanes; Transition metals

Indexed keywords

CHEMICAL BONDS; HYDROGEN; IONS; TRANSITION METALS;

COORDINATION MODES; MOLECULAR DEVICES; NONCOVALENT INTERACTIONS; ROTAXANES;

ISOMERIZATION;

EID: 29544451734     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501761     Document Type: Article

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98. 1H NMR spectroscopy.
99. 6]acetone was used throughout.
100. 1-tBu base (N′-tert-butyl-N,N, N′,N′,N″,N″-hexamethylphosphorimidic triamide) [R. Schwesinger, C. Hasenfratz, H. Schlemper, L. Walz, E.-M. Peters, K. Peters, H. G. von Schnering, Angew. Chem. 1993, 105, 1420-1422;
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102. Without this discrimination, the more-complicated molecular shuttle system containing multiple amide groups would not be able to function.