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Volumn 324, Issue 1 SPEC. ISS., 2006, Pages 280-290

Models of charge transport and transfer in molecular switch tunnel junctions of bistable catenanes and rotaxanes

Author keywords

Hopping; Molecular electronics; Molecular machines; Raman spectroscopy; Tunneling

Indexed keywords


EID: 33646267676     PISSN: 03010104     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemphys.2005.12.031     Document Type: Article
Times cited : (44)

References (71)
  • 5
    • 84924156123 scopus 로고    scopus 로고
    • Cambridge University Press, Cambridge
    • Datta S. Quantum Transport (2005), Cambridge University Press, Cambridge
    • (2005) Quantum Transport
    • Datta, S.1
  • 52
    • 33646255484 scopus 로고    scopus 로고
    • note
    • I-V measurements are typical for molecular junctions, see Refs. [10-16,18,22-27,49,50].
  • 58
    • 33646235220 scopus 로고    scopus 로고
    • note
    • Compare the data for the catenanes in Fig. 2 of Ref. [29] and for the rotaxane in Fig. 5 of Ref. [30].
  • 59
    • 33646232032 scopus 로고    scopus 로고
    • note
    • {radical dot}/3+, respectively.
  • 61
    • 33645458306 scopus 로고    scopus 로고
    • We assume that oxidation generates a net repulsion of ∼6 kcal/mol (see: S. Nygaard, B.W. Laursen, A.H. Flood, C. Hansen, J.O. Jeppesen, J.F. Stoddart, Chem. Commun. (2006) 144) lowering the barrier that was raised an extra ∼6 kcal/mol by the constricted device environment, (Ref. [45]) thus defining an effective barrier of ∼16 kcal/mol.
  • 62
    • 33646253713 scopus 로고    scopus 로고
    • note
    • The rate constants are not labeled explicitly. They will be different, however, depending upon which bias is being applied ±2 V, and which co-conformation the rotaxanes are in, GSCC or MSCC.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.