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Compare the data for the catenanes in Fig. 2 of Ref. [29] and for the rotaxane in Fig. 5 of Ref. [30].
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We assume that oxidation generates a net repulsion of ∼6 kcal/mol (see: S. Nygaard, B.W. Laursen, A.H. Flood, C. Hansen, J.O. Jeppesen, J.F. Stoddart, Chem. Commun. (2006) 144) lowering the barrier that was raised an extra ∼6 kcal/mol by the constricted device environment, (Ref. [45]) thus defining an effective barrier of ∼16 kcal/mol.
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The rate constants are not labeled explicitly. They will be different, however, depending upon which bias is being applied ±2 V, and which co-conformation the rotaxanes are in, GSCC or MSCC.
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