Toward chemically controlled nanoscale molecular machinery

Angewandte Chemie - International Edition

Volumn 42, Issue 13, 2003, Pages 1491-1495

  Tseng, Hsian Rong ^a   Vignon, Scott A ^a   Stoddart, J Fraser ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Chemical switching; Molecular devices; Rotaxanes self assembly; Supramolecular chemistry

Indexed keywords

MOLECULAR STRUCTURE; NANOSTRUCTURED MATERIALS;

MECHANICAL DISPLACEMENT;

REDOX REACTIONS;

CATENANE; OXIDIZING AGENT; ROTAXANE;

ARTICLE; CHEMICAL INTERACTION; ELECTRONICS; GEOMETRY; MACHINE; MOLECULE; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTITATIVE ANALYSIS; SEMICONDUCTOR; SPECTRUM; STIMULATION; STIMULUS; SUPRAMOLECULAR CHEMISTRY;

EID: 0037418978     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200250453     Document Type: Article

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77. 1H DQF-COSY spectrum reproduced in Figure 4.
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79. 1H DQF-COSY spectrum (Figure 4) for the oxidized [2]rotaxane. Additional evidence to support the assignments was obtained by peak integrations, as well as by monitoring the peaks during titration with the oxidant. Similar dramatic chemical shift changes have been observed in our laboratory for other TTF-containing compounds upon oxidation.
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