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Volumn 128, Issue 17, 2006, Pages 5859-5876

C7 and C9 carbon-rich bridges in diruthenium systems: Synthesis, spectroscopic, and theoretical investigations of different oxidation states

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CHEMICAL BONDS; COMPLEXATION; ELECTROCHEMISTRY; OXIDATION; RUTHENIUM COMPOUNDS;

EID: 33646707269     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0603453     Document Type: Article
Times cited : (97)

References (189)
  • 1
    • 84890621213 scopus 로고
    • For reviews on electron transfer in mixed-valence systems, see: (a) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1-73.
    • (1983) Prog. Inorg. Chem. , vol.30 , pp. 1-73
    • Creutz, C.1
  • 3
    • 0004122810 scopus 로고    scopus 로고
    • Balzani, V., Ed.; Wiley-VCH: Weinheim, Germany, Chapter 10
    • (c) Nelsen, S. F. In Electron Transfer in Chemistry; Balzani, V., Ed.; Wiley-VCH: Weinheim, Germany, 2001; Vol. 1, Chapter 10.
    • (2001) Electron Transfer in Chemistry , vol.1
    • Nelsen, S.F.1
  • 4
    • 0004122810 scopus 로고    scopus 로고
    • Balzani, V., Ed.; Wiley-VCH: Weinheim, Germany, Chapter 1
    • (d) Launay, J.-P.; Coudret, C. In Electron Transfer in Chemistry; Balzani, V., Ed.; Wiley-VCH: Weinheim, Germany, 2001; Vol. 5, Chapter 1.
    • (2001) Electron Transfer in Chemistry , vol.5
    • Launay, J.-P.1    Coudret, C.2
  • 13
    • 0031849107 scopus 로고    scopus 로고
    • Aviram, A., Ratner, M. A., Eds.; Annals of the New York Academy of Sciences, New York Academy of Sciences: New York
    • (d) Molecular Electronics: Science and Technology; Aviram, A., Ratner, M. A., Eds.; Annals of the New York Academy of Sciences, Vol. 852; New York Academy of Sciences: New York, 1998.
    • (1998) Molecular Electronics: Science and Technology , vol.852
  • 17
    • 0342517062 scopus 로고    scopus 로고
    • (d) Tour, J. M. Chem. Rev. 1996, 96, 537-554.
    • (1996) Chem. Rev. , vol.96 , pp. 537-554
    • Tour, J.M.1
  • 19
    • 0004011208 scopus 로고    scopus 로고
    • Joachim, C., Roth, S., Eds.; Kluwer: Dordrecht, The Netherlands
    • (f) Atomic and Molecular Wires; Joachim, C., Roth, S., Eds.; Kluwer: Dordrecht, The Netherlands, 1997.
    • (1997) Atomic and Molecular Wires
  • 48
    • 27144437246 scopus 로고    scopus 로고
    • (b) Ren, T. Organometallics 2005, 24, 4854-4870.
    • (2005) Organometallics , vol.24 , pp. 4854-4870
    • Ren, T.1
  • 127
    • 33646702735 scopus 로고    scopus 로고
    • note
    • No H atoms could be located in the vicinity of C4 that accounts for the inversion centre; hence the four C-C bond lengths are identical within the ring.
  • 131
    • 0034595418 scopus 로고    scopus 로고
    • (a) This cumulene was successfully isolated only with Ir and with Mn complexes; see: Ilg, K.; Werner, H. Angew. Chem., Int. Ed. 2000, 39, 1632-1634.
    • (2000) Angew. Chem., Int. Ed. , vol.39 , pp. 1632-1634
    • Ilg, K.1    Werner, H.2
  • 134
    • 33646697650 scopus 로고    scopus 로고
    • note
    • + that should be the driving force of the reaction.
  • 135
    • 33646676654 scopus 로고    scopus 로고
    • note
    • 31P NMR monitoring of the reaction that shows transient signals attributed to the intermediate [B] bearing an enynyl moiety (δ = 53.6 ppm) and an allenylidene moiety (δ = 43.2 ppm) and to the deprotonated complex 8b (δ = 51.2 ppm).
  • 136
    • 0001661427 scopus 로고
    • 5 Ruthenium complex, but without cyclization owing to the bulky ligands. See: Selegue. J. P. J. Am. Chem. Soc. 1983, 105, 5921-5923.
    • (1983) J. Am. Chem. Soc. , vol.105 , pp. 5921-5923
    • Selegue, J.P.1
  • 137
    • 33646677624 scopus 로고    scopus 로고
    • note
    • + as a byproduct.
  • 138
  • 139
    • 0346754826 scopus 로고    scopus 로고
    • (b) Bruce, M. I. Chem. Rev. 1998, 98, 2797-2858.
    • (1998) Chem. Rev. , vol.98 , pp. 2797-2858
    • Bruce, M.I.1
  • 162
    • 33646675726 scopus 로고    scopus 로고
    • note
    • 2]; however the values are close enough to observe a slight displacement of the equilibrium and to see the reduced species.
  • 163
    • 33646693987 scopus 로고    scopus 로고
    • note
    • 2 followed by reoxidation with 1 equiv of ferricinium salt 30 min later also led to the almost complete recovery of the starting complexes in the case of 5a,c (>90%).
  • 166
    • 33646710046 scopus 로고    scopus 로고
    • note
    • 2+ the symmetry is slightly broken. Nevertheless, the characteristics are still very similar to those of the other complexes. suggesting also a completely delocalized compound to which we applied the same Hush treatment.
  • 168
    • 33646714047 scopus 로고    scopus 로고
    • note
    • Similar measurements could not be conducted in more polar solvents such as methanol or acetonitrile for solubility or stability reasons.
  • 172
    • 33646679768 scopus 로고    scopus 로고
    • note
    • 9 [7][OTf] complexes leading to mixtures of unidentified products.
  • 177
    • 0004066445 scopus 로고    scopus 로고
    • Vrije Universiteit: Amsterdam, The Netherlands, SCM
    • ADF2004.01, Theoretical Chemistry. Vrije Universiteit: Amsterdam, The Netherlands, SCM.
    • Theoretical Chemistry
  • 185


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.