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Volumn 19, Issue 6, 2000, Pages 1035-1043

Molecular wires: Synthesis and properties of the new mixed-valence complex [Cp*(dppe)Fe-C≡C-X-C≡C-Fe(dppe)Cp*][PF6] (X = 2,5 -C4H2S) and comparison of its properties with those of the related all-carbon-bridged complex (X = -C4-)

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Indexed keywords


EID: 0001445645     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9908231     Document Type: Review
Times cited : (131)

References (76)
  • 24
    • 3743155296 scopus 로고    scopus 로고
    • note
    • Fermi coupling is an intramolecular process, and therefore the same splitting is expected in the solid state and in solution, as was usually observed in the other mentioned cases. In first approximation, solvation should only broaden the IR absorption peaks, and therefore at least the envelope of the Fermi doublet should be present.
  • 33
    • 3743079543 scopus 로고    scopus 로고
    • note
    • One referee suggested to us that the broadness of the corresponding IR band in solution could also be explained by the presence of valence isomers in solution, where internal rotations, counterion positions, and solvation should be frozen at the electronic time scale and possibly also at the vibrational time scale.
  • 53
    • 3743149649 scopus 로고    scopus 로고
    • Weyland, T.; Lapinte, C. Work in progress
    • Weyland, T.; Lapinte, C. Work in progress.
  • 59
    • 85088716123 scopus 로고    scopus 로고
    • note
    • 3CN, clearly shows that the position of the band B is much more sensitive to the solvent polarity than that band A is. This strongly supports the class II and class III character of the ICT corresponding to the bands B and A, respectively.
  • 63
    • 85088717870 scopus 로고    scopus 로고
    • note
    • 66,75
  • 74
    • 85088716936 scopus 로고    scopus 로고
    • note
    • p, maximum peak temperature). See ref 76.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.