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Volumn 126, Issue 45, 2004, Pages 14822-14831

Strong electronic coupling between dimolybdenum units linked by the N,N′-dimethyloxamidate anion in a molecule having a heteronaphthalene-like structure

Author keywords

[No Author keywords available]

Indexed keywords

INFRARED RADIATION; NEGATIVE IONS; OXIDATION; PARAMAGNETISM;

EID: 8844266948     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046775f     Document Type: Article
Times cited : (54)

References (86)
  • 16
    • 0034681578 scopus 로고    scopus 로고
    • and references therein
    • See for example: Nelsen, S. F. Chem. Eur. J. 2000, 6, 581 and references therein.
    • (2000) Chem. Eur. J. , vol.6 , pp. 581
    • Nelsen, S.F.1
  • 62
    • 0004150157 scopus 로고    scopus 로고
    • Bruker Analytical X-ray Systems, Inc.: Madison, WI
    • Sheldrick, G. M., SHELXTL. Version 6.12; Bruker Analytical X-ray Systems, Inc.: Madison, WI, 2000.
    • (2000) SHELXTL. Version 6.12
    • Sheldrick, G.M.1
  • 66
    • 8844234587 scopus 로고    scopus 로고
    • note
    • 2Cl, a = 17.303(1), b = 17.590(1), and c = 36.537(1) Å, β = 96.952(2)°; Mo(1)-Mo(2) = 2.11(1) Å, Mo(3)-Mo(4) = 2.12(1) Å.
  • 67
    • 8844237234 scopus 로고    scopus 로고
    • note
    • To our knowledge, this is the only known example in which the neutral, singly oxidized, and doubly oxidized species have been structurally characterized.
  • 71
    • 8844267258 scopus 로고    scopus 로고
    • note
    • Following the suggestion of a reviewer, an S = 0 unrestricted geometry optimization for the model of 3 was also performed. The resulting geometrical parameters between the two calculations were essentially identical.
  • 79
    • 8844222355 scopus 로고    scopus 로고
    • note
    • 2.
  • 80
    • 8844278695 scopus 로고    scopus 로고
    • note
    • 2] species connected by polyunsaturated dicarboxylate anions. See ref 13 b.
  • 86
    • 8844222911 scopus 로고    scopus 로고
    • note
    • 2S(S + 1).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.