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Volumn 21, Issue 13, 2002, Pages 2654-2661

Ruthenium acetylide oxidation: From stable radicals to allenylidene synthesis via γ-elimination of H+

Author keywords

[No Author keywords available]

Indexed keywords

CATIONIC RADICALS;

EID: 0012830960     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0200555     Document Type: Article
Times cited : (45)

References (57)
  • 16
    • 0038699989 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford
    • (a) Hill, H. Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, 1995; Vol. 7, pp 411-417.
    • (1995) Comprehensive Organometallic Chemistry II , vol.7 , pp. 411-417
    • Hill, H.1
  • 42
    • 0038023513 scopus 로고    scopus 로고
    • +]/[1] of 40/60, see ref b
    • +]/[1] of 40/60, see ref b.
  • 44
    • 0037685615 scopus 로고    scopus 로고
    • note
    • -1, V vs ferrocene).
  • 45
    • 49249143757 scopus 로고
    • Hydrolysis of metal vinylidenes has already been reported to give carbonyl species and the unsatured hydrocarbon derived from the homologation of vinylidene substituent. See: (a) Bruce, M. I.; Swincer, A. G.; Wallis, R. C. J. Organomet. Chem. 1979, 171, C5.
    • (1979) J. Organomet. Chem. , vol.171
    • Bruce, M.I.1    Swincer, A.G.2    Wallis, R.C.3
  • 46
    • 0029980938 scopus 로고    scopus 로고
    • (b) Bianchini, C.; Cazares, J. A.; Peruzzini, M.; Romerosa, A.; Zanobini, F. J. Am. Chem. Soc 1996, 118, 4585. However in the present case, 7 is not sensitive to hydrolysis on the time scale of the reaction, and 8 then results from the hydrolysis of the radical intermediate.
    • (1996) J. Am. Chem. Soc , vol.118 , pp. 4585
    • Bianchini, C.1    Cazares, J.A.2    Peruzzini, M.3    Romerosa, A.4    Zanobini, F.5
  • 50
    • 5244284889 scopus 로고
    • For examples see: (a) Bruce, M. I. Chem. Rev 1991, 91, 197.
    • (1991) Chem. Rev , vol.91 , pp. 197
    • Bruce, M.I.1
  • 54
    • 0038361668 scopus 로고
    • The ESR signal of ferrocenium is too broad to be detectable above 78 K. See: Pins, R.; Reinders, F. J. J. Am, Chem. Soc. 1989, 91, 4929.
    • (1989) J. Am, Chem. Soc. , vol.91 , pp. 4929
    • Pins, R.1    Reinders, F.J.2
  • 55
    • 0038361667 scopus 로고    scopus 로고
    • note
    • III species either.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.