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Volumn 22, Issue 17, 2003, Pages 3485-3494

Intermetal coupling in [(η5-C5R 5)Fe(dppe)]2(μ-CH=CHCH=CH) and in their dicationic and monocationic mixed-valence forms

Author keywords

[No Author keywords available]

Indexed keywords

COUPLING PARAMETERS;

EID: 0041825169     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0300979     Document Type: Article
Times cited : (58)

References (79)
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    • Robertson, N.; McGowan, C. A. Chem. Soc. Rev. 2003, 32, 96-103. Molecular wires composed of transition metals linked by linear carbon chains have been studied by a number of researchers. For a review, see ref 5a. For early papers, see: (a) Worth, G. H.; Robinson, B. H.; Simpson, J. Organometallics 1992, 11, 3863-3874. (b) Le Narvor, N.; Lapinte, C. Chem. Commun. 1993, 357-359. (c) Zhou, Y.; Seyler, J. W.; Weng, W.; Arif, A. M.; Gladysz, J. A. J. Am. Chem. Soc. 1993, 115, 8509-8510. (d) Yam, V. W.-W.; Lau, V. C.-Y.; Cheung, K.-K. Organometallics 1996, 15, 1740-1744.
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    • note
    • The low-temperature reaction to form 10 was only started at low temperature and then the mixture was warmed to room temperature.
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    • 7c
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    • See, for example, refs 1-5.
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    • A similar argument for various redox compounds appears in ref 15a.
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    • note
    • In these complexes, both π orbitals are expected to be bonding orbitals, though antibonding with respect to the Fe-C bonds, See Figure 3.
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    • note
    • -1, consistent with a bridge C=C stretch.
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    • UV-vis spectra have not been reported for 8 or its oxidized forms.
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    • Churchill, M. R.; Wormald, J. Inorg. Chem. 1989, 8, 1936-1941. A different crystal structure puts the angle at 126°: Davis, R. E. Chem. Commun. 1968, 1218-1219.
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    • note
    • The UV-vis spectrum of 7, as recorded by us, shows a similar tailing absorption in the visible region, but without perceptible shoulders.
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    • note
    • Our use of crystal structures to propose conformational effects in solution is admittedly speculative.
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