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0343969487
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6
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0000449516
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38
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0343969486
-
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pp value of ca. 8 Hz
-
pp value of ca. 8 Hz.
-
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39
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0343969485
-
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-1), see ref 18
-
-1), see ref 18.
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37049085698
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0342663445
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Solvation energies also affect E° values. Comparisons of the electron-releasing abilities of the metal endgroups are valid only if the relative solvation energies of the various oxidation states of 1a, 1b, 3a,b, 9, 10, and 13 do not differ significantly
-
Solvation energies also affect E° values. Comparisons of the electron-releasing abilities of the metal endgroups are valid only if the relative solvation energies of the various oxidation states of 1a, 1b, 3a,b, 9, 10, and 13 do not differ significantly.
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0007481986
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0343969483
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0001341870
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For ESR measurements of rhenium-centered radicals, see: (a) Klein, A.; Vogler, C.; Kaim, W. Organometallics 1996, 15, 236-244.
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37049074681
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60
-
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0004236045
-
-
VCH: New York
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B is the Bolzman constant, and C is the positive temperature-independent contribution for the coupling of the ground Kramers doublet with the excited levels through the Zeeman perturbation, see: Kahn, O. Molecular Magnetism; VCH: New York, 1993; p 107.
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Kahn, O.1
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61
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0001229773
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62
-
-
0343533699
-
-
1H NMR spectrum
-
1H NMR spectrum.
-
-
-
-
63
-
-
0000875039
-
-
This represents a typical LF-metal centered transition of an Fe(III) radical. These are usually observed in fully oxidized iron alkynyl complexes. See: Le Stang, S.; Paul, F.; Lapinte, C. Inorg. Chim. Acta 1999, 291, 403-425.
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Le Stang, S.1
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64
-
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0342663444
-
-
-3 M). If the linear domain of the Beer-Lambert law is exceeded, the extinction coefficient can be slightly underestimated
-
-3 M). If the linear domain of the Beer-Lambert law is exceeded, the extinction coefficient can be slightly underestimated.
-
-
-
-
68
-
-
0010133085
-
-
The class I/II/III categories of mixed-valence complexes signify that the odd electron is (I) localized on one metal, (II) predominantly localized on one metal, but that the complex has an energetically accessible state whereby the electron becomes predominantly localized on the other metal, and (III) fully delocalized over both metals
-
Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 247-422. The class I/II/III categories of mixed-valence complexes signify that the odd electron is (I) localized on one metal, (II) predominantly localized on one metal, but that the complex has an energetically accessible state whereby the electron becomes predominantly localized on the other metal, and (III) fully delocalized over both metals.
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Adv. Inorg. Chem. Radiochem.
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Robin, M.B.1
Day, P.2
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71
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0000045929
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(b) Chou, M. H.; Creutz, C.; Sutin, N. Inorg. Chem. 1992, 31, 2318-2327.
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0032557236
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Patoux, C.; Launay, J.-P.; Beley, M.; Chodorowski-Kimmes, S.; Collin, J. P.; James, S.; Sauvage, J. P. J. Am. Chem. Soc. 1998, 120, 3717-3725.
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Sauvage, J.P.7
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77
-
-
0343533697
-
-
note
-
In the case that no precipitation occurs after 48 h, solvent is removed from the dark green reaction mixture by oil pump vacuum. The dark green residue is extracted with toluene (4 × 5 mL) until the purple extracts become colorless. The toluene is removed by vacuum and the deep purple residue is washed with MeOH (4 × 5 mL, until the purple washings become colorless) and pentane (2 × 3 mL) and dried by oil pump vacuum. The remaining orange solid 9 can then be further purified.
-
-
-
-
78
-
-
0342663442
-
-
IR data are given in Table 1
-
IR data are given in Table 1.
-
-
-
-
79
-
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0004178247
-
-
An Interaccive Intelligent System for Crystal Structure Analysis; ENRAF-NONIUS: Delft, The Netherlands
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Fair, C. K. MolEN. An Interaccive Intelligent System for Crystal Structure Analysis; ENRAF-NONIUS: Delft, The Netherlands, 1990.
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MolEN
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Fair, C.K.1
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80
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0003585022
-
-
Program for Handling of CAD4-Diffractometer Output SHELX(S/L); Utrecht University: Utrecht, The Netherlands
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Spek, A. L. HELENA. Program for Handling of CAD4-Diffractometer Output SHELX(S/L); Utrecht University: Utrecht, The Netherlands, 1997.
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HELENA
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Spek, A.L.1
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81
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0004258867
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