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Volumn 9, Issue 14, 2003, Pages 3324-3340

Synthesis, structure, and reactivity of sp carbon chains with bis(phosphine) pentafluorophenylplatinum endgroups: Butadiynediyl (C4) through hexadecaoctaynediyl (C16) bridges, and beyond

Author keywords

Carbyne; Crystal structures; Oxidative coupling; Platinum; Polyynes

Indexed keywords

CHEMICAL BONDS; CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PLATINUM COMPOUNDS; POLYMERIZATION; REACTION KINETICS; REDOX REACTIONS; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY;

EID: 0042347472     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200204741     Document Type: Article
Times cited : (144)

References (113)
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    • Note
    • 12Pt.
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    • 8Pt and higher homologues - where abrupt changes would be less likely, the π → π* transitions can be assigned with good confidence, and endgroup effects play a smaller role - have been utilized.
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    • Note
    • 5 carbon was not observed.
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    • 0043097059 scopus 로고    scopus 로고
    • Note
    • 195Pt = 33.8%), and is not reflected in the peak multiplicity given.
  • 103
    • 0042596172 scopus 로고    scopus 로고
    • Note
    • m/z (FAB, 3-NBA) for the most intense peak of the isotope envelope. For some compounds, the most strongest signal is matrix-derived and no ion of 100% intensity is specified.
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    • The butadiyne concentration is calculated from the mass increase of the THF solution. CAUTION: this explosive compound was generated and handled as described in L. Brandsma, H. D. Verkruijsse, Synthesis of Acetylenes, Allenes and Cumulenes, Elsevier, New York, 1981, p. 146.
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    • Note
    • For TGA, IR, and/or UV/Vis data, see Tables 1, 2 and 4.
  • 106
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    • Note
    • 31P NMR data, see Table 2.
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    • Note
    • The initial addition was ca. 14 mL (for this homocoupling, lesser amounts appeared to generate a precipitate). Then several smaller portions were added until ca. 20 mL was reached.
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    • Note
    • A satisfactory microanalysis was not obtained for this compound.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.