The localized-to-delocalized transition in mixed-valence chemistry

Chemical Reviews

Volumn 101, Issue 9, 2001, Pages 2655-2685

  Demadis, Konstantinos D ^a,d   Hartshorn, Chris M ^b,d   Meyer, Thomas J ^c,d  

^a C/o Naval Research Laboratory ^*  (Greece)

^b NAVAL RESEARCH LABORATORY   (United States)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

^d University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON TRANSFER;

DIMERS; ELECTROSTATICS; PERTURBATION TECHNIQUES; RATE CONSTANTS; SOLVENTS; STRUCTURE (COMPOSITION);

IRON COMPOUNDS;

EID: 0035470233     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr990413m     Document Type: Article

References (323)

1. Mixed Valence Compounds; Brown, D.M., Ed.; D. Reidel: Dordrecht, Holland, 1980.
2. Mixed Valence Systems: Applications in Chemistry, Physics and Biology; Prassides, K., Ed.; NATO ASI Series 343; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1990.
3. Woodward, J. Philos. Trans. R. Soc. London 1724, 33, 15.
4. Creutz, C.; Taube, H. J. Am. Chem. Soc. 1969, 91, 3988.
5. Creutz, C.; Taube, H. J. Am. Chem. Soc. 1973, 95, 1086.
6. Cowan, D.O.; Levanda, C.; Park, J.; Kaufman, F. Acc. Chem. Res. 1973, 6, 1.
7. Le Vanda, C.; Bechgaard, K.; Cowan, D.O.; Rausch, M.D. J. Am. Chem. Soc. 1977, 99, 2964.
8. Robin, M.B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
9. Allen, G.C.; Hush, N.S. Prog. Inorg. Chem. 1967, 8, 357.
10. Powers, M.J.; Meyer, T.J. J. Am. Chem. Soc. 1980, 102, 1289.
11. Meyer, T. J. Acc. Chem. Res. 1978, 11, 94.
12. Nelsen, S.F.; Ismagilov, R.F.; Trieber, D.A., II Science 1997, 278, 846.
13. Nelsen, S.F.; Ismagilov, R.F.; Powell, D.R. J. Am. Chem. Soc. 1997, 119, 10213.
14. Nelsen, S.F.; Ismagilov, R.F.; Powell, D.R. J. Am. Chem. Soc. 1998, 120, 1924.
15. Nelsen, S.F.; Adamus, J.; Wolff, J.J. J. Am. Chem. Soc. 1994, 116, 1589.
16. Nelsen, S.F.; Trieber, D.A., II; Wolff, J.J.; Powell, D.R.; Rogers-Crowley, S. J. Am. Chem. Soc. 1997, 119, 6873.
17. Nelsen, S.F.; Ismagilov, R.F.; Gentile, K.E.; Powell, D.R. J. Am. Chem. Soc. 1999, 121, 7108.
18. Elliott, C.M.; Derr, D.L.; Matyushov, D.V.; Newton, M.D. J. Am. Chem. Soc. 1998, 120, 11714.
19. Hush, N.S. Prog. Inorg. Chem. 1967, 8, 391.
20. Hush, N.S. Electrochim. Acta 1968, 13, 1005.
21. Crutchley, R. J. Adv. Inorg. Chem. 1994, 41, 273.
22. Ward, M.D. Chem. Soc. Rev. 1995, 187.
23. Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
24. Kaim, W.; Bruns, W.; Poppe, J.; Kasack, V. J. Mol. Struct. 1993, 292, 221.
25. Richardson, D.E.; Taube, H. Coord. Chem. Rev. 1984, 60, 107.
26. Chen, P.; Meyer, T. J. Chem. Rev. 1998, 98, 1439.
27. Horng, M.L.; Gardecki, J.A.; Papazyan, A.; Maroncelli, M. J. Phys. Chem. 1995, 99, 17311.
28. Kahlow, M.A.; Kang, T.J.; Barbara, P.F. J. Phys. Chem. 1987, 91, 6452.
29. Fleming, G.R.; Cho, M. Annu. Rev. Phys. Chem. 1996, 47, 109.
30. (a) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441.
31. (b) Brunschwig, B.S.; Sutin, N.; Coord. Chem. Rev. 1999, 187, 233.
32. (c) Sutin, N. Adv. Chem. Phys. 1999, 106, 7.
33. Newton, M.D. Adv. Chem. Phys. 1999, 106, 303.
34. Hupp, J.T.; Dong, Y.; Blackburn, R.L.; Lu, H. J. Phys. Chem. 1993, 97, 3278.
35. Mataga, N.; Kubota, T. Molecular Interactions and Electronic Spectra; Dekker: New York, 1970.
36. Bublitz, G.U.; Laidlaw, W.M.; Denning, R.G.; Boxer, S.G. J. Am. Chem. Soc. 1998, 120, 6068.
37. Creutz, C.; Newton, M.D.; Sutin, N. J. Photochem. Photobiol. A: Chem. 1994, 82, 47.
38. Hush, N.S. Trans. Faraday Soc. 1961, 57, 557.
39. 5 electronic core.
40. IT/δT = - ΔS° where ΔS° is the entropy difference between the initial and final states. See: Hupp, J.; Neyhart, G.; Meyer, T.J.; Kober, E.K. J. Phys. Chem. 1992, 96, 10820.
41. b〉.
42. Mulliken, R.S. J. Am. Chem. Soc. 1952, 64, 811.
43. Mulliken, R.S.; Person, W.B. Molecular Complexes; Wiley: New York, 1969.
44. Reimers, J.R.; Hush, N.S. J. Am. Chem. Soc. 1995, 117, 1302.
45. Salaymeh, F.; Berhane, S.; Yusof, R.; de la Rosa, R.; Fung, E.Y.; Matamoros, R.; Lan, K.W.; Zheng, Q.; Kober, E.M.; Curtis, J.C. Inorg. Chem. 1993, 32, 3895.
46. Nelsen, S.F.; Newton, M.D. J. Phys. Chem. A 2000, 104, 10023.
47. (a) Oh, D.H.; Boxer, S.G. J. Am. Chem. Soc. 1990, 112, 8161.
48. (b) Karki, L.; Lu, H.P.; Hupp, J.T. J. Phys. Chem. 1996, 100, 15637.
49. Bublitz, G.U.; Boxer, S.G. Annu. Rev. Phys. Chem. 1997, 48, 213.
50. Nelsen, S.F. Chem. Eur. J. 2000, 6, 581.
51. Lambert, C.; Nöll, G. J. Am. Chem. Soc. 1999, 121, 8434.
52. Huttner, G.; Evertz, K. Acc. Chem. Res. 1986, 19, 406.
53. Hush, N.S. NATO Adv. Study Inst., Ser. C 1980, 58, 151.
54. Reimers, J.R.; Hush, N.S. Chem. Phys. 1996, 208, 177.
55. Piepho, S.B. J. Am. Chem. Soc. 1988, 110, 6319.
56. Amos, A.T.; Burrows, B.L. Adv. Quantum Chem. 1973, 7, 289.
57. Liptay, W. In Excited States; Lim, E.C., Ed.; Academic Press: New York, 1974; Vol. 1, p 129.
58. Liptay, W. Angew. Chem., Int. Ed. Engl. 1969, 8, 177.
59. Piepho, S.B.; Krausz, E.R.; Schatz, P.N. J. Am. Chem. Soc. 1978, 100, 2996.
60. Wong, K.Y.; Schatz, P.N. Prog. Inorg. Chem. 1981, 28, 369.
61. Schatz, P.N. NATO Adv. Study Inst., Ser. C 1980, 58, 115.
62. Fulton, R.L.; Gouterman, M. J. Phys. Chem. 1961, 35, 1059.
63. Rice, M.J.; Lipari, N.O.; Strässler, S. Phys. Rev. Lett. 1977, 39, 1359.
64. Rice, M. J. Phys. Rev. Lett. 1976, 37, 36.
65. Rice, M.J.; Yartsev, V.M.; Jacobsen, C.S. Phys. Rev. B 1980, 21, 3437.
66. a1g, totally symmetric Fe-O stretch. The coordinate in the original PKS treatment is an antisymmetric linear combination of such local modes. In the delocalized limit, the local modes are coupled to give a symmetric-antisymmetric pair. The degree to which they differ in energy depends on the extent of the Fermi resonance interactien between them. If there is a change in symmetry on electron transfer, local asymmetric modes are also coupled to electron transfer and must be included in the analysis.
67. Hush, N.S. ACS Symp. Ser. 1982, 198, 201.
68. Prassides, K.; Schatz P.N. J. Phys. Chem. 1989, 93, 8387.
69. Ko, J.; Ondrechen, M. J. Chem. Phys. Lett. 1984, 112, 507.
70. Ko, J.; Ondrechen, M.J. J. Am. Chem. Soc. 1985, 107, 6161.
71. Ondrechen, M.J.; Ferretti, A.; Lami, A.; Villani, G. J. Phys. Chem. 1994, 98, 11230.
72. Ferretti, A.; Lami, A.; Ondrechen, M.J.; Villani, G. J. Phys. Chem. 1995, 99, 10484.
73. Murga, L.F.; Ondrechen, M. J. Theor. Chim. Acta 1995, 90, 331.
74. Schatz, P.N. NATO Adv. Study Inst., Ser. C 1991, 343, 7.
75. Creutz, C.; Chou, M.H. Inorg. Chem. 1987, 26, 2995.
76. Oh, D.H.; Sane, M.; Boxer, S.G. J. Am. Chem. Soc. 1991, 113, 6880.
77. Stebler, A.; Ammeter, J.H.; Fürholz, U.; Ludi, A. Inorg. Chem. 1984, 23, 2764.
78. Beattie, J.K.; Hush, N.S.; Taylor, P.R. Inorg. Chem. 1976, 15, 992.
79. Best, S.P.; Clark, R.J.H.; McQueen, R.C.S.; Joss, S. J. Am. Chem. Soc. 1989, 111, 548.
80. Piepho, S.B. J. Am. Chem. Soc. 1990, 112, 4197.
81. Broo, A.; Lincoln, P. Inorg. Chem. 1997, 36, 2544.
82. Lauher, J.W. Inorg. Chim. Acta 1980, 39, 119.
83. Broo, A.; Larsson, S. Chem. Phys. 1982, 161, 363.
84. (a) Ondrechen, M.J.; Ko, J.; Root, L.J. J. Phys. Chem. 1984, 88, 5919.
85. (b) Zhang, L.T.; Ko, J.; Ondrechen, M.J. J. Phys. Chem. 1989, 93, 3030.
86. Ferretti, A.; Lami, A.; Villani, G. Inorg. Chem. 1998, 37, 2799.
87. Bencini, A.; Ciofini, I.; Daul, C.A.; Ferretti, A. J. Am. Chem. Soc. 1999, 121, 11418.
88. Fürholz, U.; Joss, S.; Bürgi, H.A.; Ludi, A. Inorg. Chem. 1985, 24, 9143.
89. Fürholz, U.; Bürgi, H.A.; Wagner, F.E.; Stebler, A.; Ammeter, J.H.; Krausz, E.; Clark, R.J.H.; Stead, M.J.; Ludi, A. J. Am. Chem. Soc. 1984, 106, 121.
90. Lu, H.; Petrov, V.; Hupp, J.T. Chem. Phys. Lett. 1995, 235, 521.
91. Powers, M.J.; Sahnon, D.J.; Callahan, R.W.; Meyer, T.J. J. Am. Chem. Soc. 1976, 98, 6731.
92. Citrin, P.H. J. Am. Chem. Soc. 1973, 95, 6472.
93. Hush, N.S. Chem. Phys. 1975, 10, 361.
94. Citrin, P.H.; Ginsberg, A.P. J. Am. Chem. Soc. 1981, 103, 3673.
95. Lazarus, M.S.; Sham, T.K. J. Am. Chem. Soc. 1979, 101, 7622.
96. Spreer, L.O.; Allan, C.B.; MacQueen, D.B.; Otvos, J.W.; Calvin, M. J. Am. Chem. Soc. 1994, 116, 2187.
97. Moscherosch, M.; Waldnör, E.; Binder, H.; Kaita, W.; Fiedler, J. Inorg. Chem. 1995, 34, 4326.
98. Demadis, K.D.; El-Samanody, E.-S.; Coia, G.M.; Meyer, T.J. J. Am. Chem. Soc. 1999, 121, 535.
99. Demadis, K.D.; Meyer, T.J.; White, P.S. Inorg. Chem. 1998, 37, 3610.
100. Richardson, D.E.; Sen, J.P.; Buhr, J.D.; Taube, H. Inorg. Chem. 1982, 21, 3136.
101. Che, C.-M.; Lam, H.-W.; Tong, W.-F.; Lai, T.-F.; Lau, T.-C. J. Chem. Soc., Chem. Commun. 1989, 1883.
102. Lam, H.-W.; Che, C.-M.; Wong, K.-Y. J. Chem. Soc., Dalton Trans. 1992, 1411.
103. 111,112). This is because the complexes themselves are unsymmetrical. There are rotamers with respect to the bridge which are not centrosymmetric for which v(pz) is weakly IR active.
104. Goodman, B.A.; Raynor, J.B. Adv. Inorg. Chem. Radiochem. 1970, 13, 135.
105. Sen, J.; Taube, H. Acta Chem. Scand. Ser. A 1979, 33, 125.
106. Buhr, J.D.; Winkler, J.R.; Taube, H. Inorg. Chem. 1980, 19, 2416.
107. Kober, E.M. Ph.D. Dissertation, University of North Carolina, 1982.
108. Kober, E.M.; Goldsby, K.A.; Narayana, D.N.S.; Meyer, T.J. J. Am. Chem. Soc. 1983, 105, 4303.
109. Hill, N.J. J. Chem. Soc., Faraday Trans. 2 1972, 68, 427.
110. Kober, E.M.; Meyer, T. J. Inorg. Chem. 1983, 22, 1614.
111. Neyhart, G.A.; Timpson, C.J.; Bates, W.D.; Meyer, T.J. J. Am. Chem. Soc. 1996, 118, 3730.
112. Hudson, A.; Kennedy, M.J. J. Chem. Soc. A 1969, 1116.
113. Bhattacharya, S.; Ghosh, P.; Chakravarty, A. Inorg. Chem. 1985, 24, 3224.
114. IC(2) are the energy spacings between the Kramer's doublets.
115. Demadis, K.D.; Neyhart, G.A.; Kober, E.M.; Meyer, T.J. J. Am. Chem. Soc. 1998, 120, 7121.
116. Demadis, K.D.; Neyhart, G.A.; Kober, E.M.; Meyer, T. J. Inorg. Chem. 1999, 38, 5948.
117. 6a. See: Lord, R.C.; Marston, A.L.; Miller, F.A. Spectrochim. Acta 1957, 9, 113 and ref 86 in this work.
118. (a) Lay, P.A.; Magnuson, R.H.; Taube, H. Inorg. Chem. 1988, 27, 2364.
119. (b) Magnuson, R.H.; Lay, P.A.; Taube, H. J. Am. Chem. Soc. 1983, 105, 2507.
120. Grevels, F.-W.; Kerpen, K.; Klotzbucher, W.E.; McClurg, R.E.D.; Russell, G.; Viotte, M.; Schaffner, K. J. Am. Chem. Soc. 1998, 120, 10423 and references therein.
121. Wu, R.; Arap Koske, S.K.; White, R.P.; Anson, C.E.; Jayasooriya, U.A.; Cannon, R.D. J. Chem. Soc., Chem. Commun. 1994, 1657.
122. Ito, T.; Hamaguchi, T.; Nagino, H.; Yamaguchi, T.; Kido, H.; Zavarine, I.S.; Richmond, T.; Washington, J.; Kubiak, C.P. J. Am. Chem. Soc. 1999, 121, 4625.
123. Ito, T.; Hamaguchi, T.; Nagino, H.; Yamaguchi, T.; Washington, J.; Kubiak, C.P. Science 1997, 277, 660.
124. Hartshorn, C.M.; Daire, N.; Tondreau, V.; Loeb, B.; Meyer, T. J. Manuscript in preparation.
125. Chin, T.T.; Grimes, R.N.; Geiger, W.E. Inorg. Chem. 1999, 38, 93.
126. Maroncelli, M. J. Mol. Liq. 1993, 57, 1.
127. Barbara, P.F.; Jarzeba, W. Adv. Photochem. 1990, 15, 1.
128. Simon, J.D. Acc. Chem. Res. 1988, 21, 128.
129. Bagchi, B.; Chandra, A. Adv. Chem. Phys. 1991, 80, 1.
130. Bagchi, B. Annu. Rev. Phys. Chem. 1989, 40, 115.
131. Raineri, F.O.; Zhou, Y.; Friedman, H.L. Chem. Phys. 1991, 152, 201.
132. Ladanyi, B.; Shaf, M.S. Annu. Rev. Phys. Chem. 1993, 44, 335.
133. Hynes, J.T. In Ultrafast Dynamics of Chemical Systems; Simon, J.D. Ed.; Klewer: Dordrecht, Holland, 1994; p 345.
134. Smith, B.B.; Kim, H.J.; Borgis, D.; Hynes, J.T. In Dynamics and Mechanism of Photoinduced Transfer and Related Phenomena; Mataga, N., Okada, T., Masuhara, H., Eds.; Elsevier: Amsterdam, Holland, 1992; p 39.
135. Kosower, E.M.; Huppert, D. Annu. Rev. Phys. Chem. 1986, 37, 127.
136. Joo, T.; Jia, Y.; Yu, J.-Y.; Lang, M.J.; Fleming, G.R. J. Chem. Phys. 1996, 104, 6089.
137. Stratt, R.M.; Cho, M. J. Chem. Phys. 1994, 100, 6700.
138. Ladanyi, B.M.; Stratt, R.M. J. Phys. Chem. 1995, 99, 2502.
139. Timpson, C.J.; Bignozzi, C.A.; Sullivan, B.P.; Kober, E.M.; Meyer, T.J. J. Phys. Chem. 1996, 100, 2915.
140. Curtis, J.C.; Sullivan, B.P.; Meyer, T. J. Inorg. Chem. 1983, 22, 224.
141. Stravrev, K.K.; Zerner, M.C.; Meyer, T.J. J. Am. Chem. Soc. 1995, 117, 8684.
142. Zeng, J.; Hush, N.S.; Reimers, J.R. J. Phys. Chem. 1996, 100, 19292.
143. Zeng, J.; Hush, N.S.; Reimers, J.R. J. Am. Chem. Soc. 1996, 118, 2059.
144. Brunschwig, B.S.; Ehrenson, S.; Sutin, N. J. Phys. Chem. 1986, 90, 3657.
145. Matyushov, D.; Schmid, R. J. Phys. Chem. 1994, 98, 5152.
146. Matyushov, D. Chem. Phys. 1993, 174, 199.
147. Hammack, W.S.; Lowery, M.D.; Hendrickson, D.N.; Drickamer, H.G. J. Phys. Chem. 1988, 92, 1771.
148. Roberts, J.A.; Hupp, J.T. Inorg. Chem. 1992, 31, 157.
149. (a) Krausz, E.R.; Mau, A.W.H. Inorg. Chem. 1986, 25, 1484.
150. (b) Krausz, E.R. Chem. Phys. Lett. 1985, 120, 113.
151. Dubicki, L.; Ferguson, J.; Krausz, E.R. J. Am. Chem. Soc. 1985, 107, 179.
152. Zeng, J.; Hush, N.S.; Reimers, J.R. J. Phys. Chem. 1995, 99, 10459.
153. Magnuson, R.H.; Taube, H. J. Am. Chem, Soc. 1975, 97, 5129.
154. Winkler, J.R.; Netzel, T.L.; Creutz, C.; Sutiu, N. J. Am. Chem. Soc. 1987, 109, 2381.
155. Oh, D.H.; Boxer, S.G. J. Am. Chem. Soc. 1989, 111, 1130.
156. Petrov, V.; Hupp, J.T.; Mottley, C.; Mann, L.C. J. Am. Chem. Soc. 1994, 116, 2171.
157. j).
158. Myers, A.B. Chem. Phys. 1994, 180, 215.
159. Heller, E. J. Acc. Chem. Res. 1981, 14, 368.
160. Zink, J.I.; Shin, K.-C.K. Adv. Photochem. 1991, 16, 119.
161. Myers, A.B. J. Phys. Chem. A 1999, 103, 6891.
162. Poppe, J.; Moscherosch, M.; Kaim, W. Inorg. Chem. 1993, 32, 2640.
163. Evans, C.E.B.; Naklicki, M.L.; Rezvani, A.R.; White, C.A.; Kondratiev, V.V.; Crutchley, R.J. J. Am. Chem. Soc. 1998, 120, 13096.
164. Wlodarczyk, A.; Doyle, G.A.; Maher, J.P.; McCleverty, J.A.; Ward, M.D. Chem. Commun. 1997, 769.
165. Kasack, V.; Kaita, W.; Binder, H.; Jordanov, J.; Roth, E. Inorg. Chem. 1995, 34, 1924.
166. Kaita, W.; Kasack, V.; Binder, H.; Roth, E.; Jordanov, J. Angew. Chem., Int. Ed. Engl. 1988, 27, 1174.
167. Newton, M.D.; Sutin, N. Annu. Rev. Phys. Chem. 1984, 35, 437.
168. Sutin, N. Acc. Chem. Res. 1982, 15, 275.
169. Marcus, R.A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265.
170. Barbara, P.F.; Meyer, T.J.; Rather, M.A. J. Phys. Chem. 1996, 100, 13148 and references therein.
171. Hush, N.S. Coord. Chem. Rev. 1985, 64, 135.
172. Kestner, N.R.; Logan, J.; Jortner, J. J. Phys. Chem. 1974, 78, 2148.
173. Jortner, J. J. Chem. Phys. 1976, 64, 4860.
174. Bixon, M.; Jortner, J. Faraday Discuss. Chem. Soc. 1982, 74, 17.
175. Bixon, M.; Jortner, J.; Cortes, J.; Heitele, H.; Michel-Beyerle, M.E. J. Phys. Chem. 1994, 98, 7289.
176. Kober, E.M.; Caspar, J.V.; Lumpkin, R.S.; Meyer, T.J. J. Phys. Chem. 1986, 90, 3722.
177. Marcus, R.A. J. Phys. Chem. 1989, 93, 3078.
178. Steinfeld, J.I. Molecules and Radiation; The MIT Press: Cambridge, 1985.
179. Kubo, R.; Toyozawa, Y. Prog. Theor. Phys. 1955, 13, 160.
180. Lax, M. J. Chem. Phys. 1952, 20, 1752.
181. Myers, A.B. Chem. Phys. 1994, 180, 215.
182. Hornung, F.M.; Baumann, F.; Kaim, W.; Olabe, J.A.; Slep, L.D.; Fiedler, J. Inorg. Chem. 1998, 37, 311.
183. Atwood, C.G.; Geiger, W.E.; Rheingold, A.L. J. Am. Chem. Soc. 1993, 115, 5310.
184. (a) Hillman, M.; Kvick, A. Organometallics. 1983, 2, 1780.
185. (b) Levanda, C.; Bechgaard, K.; Cowan, D.O.; Mueller-Westerhoff, U.T.; Elbrecht, P.; Candeta, G.A.; Collins, R.L. J. Am. Chem. Soc. 1976, 98, 3181.
186. Kirchner, R.F.; Loew, G.H.; Mueller-Westerhoff, U.T. Inorg. Chem. 1976, 15, 2665.
187. Dubicki, L.; Ferguson, J.; Krausz, E.R.; Lay, P.A.; Maeder, M.; Taube, H. J. Phys. Chem. 1984, 88, 3940.
188. Lay, P.A.; Magnuson, R.H.; Sen, J.; Taube, H. J. Am. Chem. Soc. 1982, 104, 7658.
189. Dubicki, L.; Ferguson, J.; Krausz, E.R.; Lay, P.A.; Maeder, M.; Magnuson, R.H.; Taube, H. J. Am. Chem. Soc. 1985, 107, 2167.
190. Tom, G.M.; Taube, H. J. Am. Chem. Soc. 1975, 97, 5310.
191. Joss, S.; Bürgi, H.B.; Ludi, A. Inorg. Chem. 1985, 24, 949.
192. Beattie, J.K.; Del Favero, P.; Hambley, T.W.; Hush, N.S. Inorg. Chem. 1988, 27, 2000.
193. Hughes, M.N.; O'Reardon, D.; Poole, R.K.; Hursthouse, M.B.; Thornton-Pert, M. Polyhedron 1987, 6, 1711.
194. Hush, N.S.; Beattie, J.K.; Ellis, V.M. Inorg. Chem. 1984, 23, 3339.
195. Armstrong, R.S.; Beattie, J.K.; Del Favero, P.; Ellis, V.M.; Hush, N.S. Inorg. Chim. Acta 1984, 89, L33.
196. Nelsen, S.F.; Tran, H.Q.; Nagy, M.A. J. Am. Chem. Soc. 1998, 120, 298.
197. Liberko, C.A.; Miller, L.L.; Katz, T.J.; Liu, L. J. Am. Chem. Soc. 1993, 115, 2478.
198. Poppe, J.; Kaim, W.; Ben Albatef, A.; Katz, N.E. J. Chem. Soc., Perkin Trans. 2 1993, 2105.
199. Bell, S.E.; Field, S.S.; Haines, R.I.; Moseherosch, M.; Matheis, W.; Kaita, W. Inorg. Chem. 1992, 31, 3269.
200. Baumann, F.; Kaim, W.; García Posse, M.; Katz, N.E. Inorg. Chem. 1998, 37, 658.
201. Seyler, J.W.; Weng, W.; Zhou, Y.; Gladysz, J.A. Organometallics 1993, 12, 3802.
202. Le Narvor, N.; Lapinte, C. J. Chem. Soc., Chem. Commun. 1993, 357.
203. Etzenhouser, B.A.; Dibiase Cavanaugh, M.; Spurgeon, H.N.; Sponsler, M.B. J. Am. Chem. Soc. 1994, 116, 2221.
204. Wlodarczyk, A.; Malher, J.P.; McCleverty, J.A.; Ward, M.D. J. Chem. Soc., Chem. Commun. 1995, 2397.
205. Bruns, W.; Kaim, W.; Waldhör, E.; Krejik, M. Inorg. Chem. 1995, 34, 663.
206. Bruns, W.; Kaita, W.; Waldhör, E.; Krejik, M. J. Chem. Soc., Chem. Commun. 1993, 1868.
207. Kaita, W.; Bruns, W.; Kohlmann, S.; Krejik, M. Inorg. Chim. Acta 1995, 229, 143.
208. Geiger, W.E.; Atwood, C.G.; Chin, T.T. Molecular Electrochemistry of Inorganic, Bioinorganic and Organometallic Compounds; NATO ASI Ser. C; Kluwer Academic Publishers: Derdrecht, The Netherlands, 1993; Vol. 385, p 519.
209. Ruminski, R.R.; Serveiss, D.; Jacquez, M. Inorg. Chem. 1995, 34, 3358.
210. Hupp, J.T.; Neyhart, G.A.; Meyer, T.J. J. Am. Chem. Soc. 1986, 108, 5349.
211. Neyhart, G.A.; Hupp, J.T.; Curtis, J.C.; Timpson, C.J.; Meyer, T.J. J. Am. Chem. Soc. 1996, 118; 3724.
212. 5 and the added solvent as donor. See: Gutmann, V. The Donor-Accepter Approach to Molecular Interactions; Plenum Press: New York, 1978.
213. Haga, M.; Matsumura-Inoue, T.; Yamabe, S. Inorg. Chem. 1987, 26, 4148.
214. (a) Stoll, M.E.; Lovelaee, S.R.; Geiger, W.E.; Schimanke, H.; Hyla-Kryspin, I.; Gleiter, R. J. Am. Chem. Soc. 1999, 121, 9343.
215. (b) Gleiter, R.; Röcker, H.; Pflästerer, G.; Treptow, B.; Kratz, D. Tetrahedron Lett. 1993, 34, 8075.
216. Dong, Y.; Hupp, J.T.; Yoon, D.I. J. Am. Chem. Sec. 1993, 125, 4379.
217. Krentzien, H.; Taube, H. J. Am. Chem. Sec. 1976, 98, 6379.
218. Cannon, R.D.; White, R.P. Prog. Inorg. Chem. 1988, 36, 195.
219. Meesuk, L.; Jayasooriya, U.A.; Cannon, R.D.; Powell, D.B. J. Am. Chem. Soc. 1987, 109, 2009.
220. Johnson, M.K.; Cannon, R.D.; Powell, D.B. Spectrochim. Acta 1982, 38A, 307.
221. Oh, S.M.; Hendrickson, D.N.; Hassett, K.L.; Davis, R.E. J. Am. Chem. Soc. 1985, 107, 8009.
222. Oh, S.M.; Wilson, S.R.; Hendrickson, D.N.; Woehler, S.E.; Wittebort, R.J.; Inniss, D.; Strouse, C.E. J. Am. Chem. Soc. 1987, 109, 1073.
223. Woehler, S.E.; Wittebort, R.J.; Oh, S.M.; Kambara, T.; Hendrickson, D.N.; Inniss, D.; Strouse, C.E. J. Am. Chem. Soc. 1987, 109, 1063.
224. Kaneke, Y.; Nakano, M.; Scrai, M.; Jang, H.G.; Hendrickson, D.N. Inorg. Chem. 1989, 28, 1067.
225. Sorai, M.; Hendrickson, D.N. Pure Appl. Chem. 1991, 63, 1503.
226. Webb, R.J.; Hagen, P.M.; Wittebort, R.J.; Sorai, M.; Hendrickson, D.N. Inorg. Chem. 1992, 31, 1791.
227. Sane, H. Hyperfine Interact. 1990, 53, 97 and references therein.
228. Konno, M.; Sane, H. Bull. Chem. Soc. Jpn. 1988, 61, 4155.
229. Dong, T.-Y.; Cohn, M.J.; Hendrickson, D.N.; Pierpont, C.G. J. Am. Chem. Soc. 1985, 107, 4777.
230. Dong, T.-Y.; Schei, C.-C.; Hsu, T.-L.; Lee, S.-L.; Li, S.-J., Inorg. Chem. 1991, 30, 2457.
231. Cohn, M.J.; Dong, T.-Y.; Hendrickson, D.N.; Geib, S.J.; Rheingold, A.L. J. Chem. Soc., Chem. Commun. 1985, 1095.
232. Dong, T.-Y.; Kambara, T.; Hendrickson, D.N. J. Am. Chem. Soc. 1986, 108, 5857.
233. Dong, T.-Y.; Huang, C.-H.; Chang, C.-K.; Wen, Y.-S.; Lee, S.-Y.; Chen, J.-A.; Yeh, W.-Y.; Yeh, A. J. Am. Chem. Soc. 1993, 115, 6357.
234. Swanton, D.J.; Bacskay, G.D.; Hush, N.S. Chem. Phys. 1986, 107, 9.
235. Swanton, D.J.; Bacskay, G.D.; Hush, N.S. Chem. Phys. 1986, 107, 25.
236. Swanton, D.J.; Bacskay, G.D.; Hush, N.S. J. Chem. Phys. 1986, 84, 5715.
237. Ulstrup, J.; Jortner, J. J. Chem. Phys. 1975, 63, 4358.
238. Jortner, J.; Bixon, M. J. Chem. Phys. 1988, 88, 167.
239. Siders, P.; Marcus, R.A. J. Am. Chem. Soc. 1981, 103, 741.
240. Siders, P.; Marcus, R.A. J. Am. Chem. Soc. 1981, 103, 748.
241. (a) Newton, M.D. Chem. Rev. 1991, 91, 767.
242. (b) Newton, M.D.; Cave, R.J. In Molecular Electronics; Jortner, J., Ratner, M.A., Eds.; Blackwell Science Ltd.: Oxford, 1997; p 73.
243. Marcus, R.A. Annu. Rev. Phys. Chem. 1966, 15, 155.
244. Marcus, R.A. Rev. Mod. Phys. 1993, 65, 599.
245. Sutin, N.; Brunschwig, B.S. ACS Symp. Ser. 1982, 198, 105.
246. Simon, J.D. Acc. Chem. Res. 1988, 21, 128.
247. Weaver, M. J. Chem. Rev. 1992, 92, 463.
248. Calef, D.F.; Wolynes, P.G. J. Phys. Chem. 1983, 87, 3387.
249. Heitele, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 359.
250. Sumi, H.; Marcus, R.A. J. Chem. Phys. 1986, 84, 4894.
251. Zusman, L.D. Chem. Phys. 1988, 119, 51.
252. Bixon, M.; Jortner, J. Chem. Phys. 1993, 176, 467.
253. Simon, J.D.; Rossky, P. J. Nature 1994, 370, 263.
254. Weaver, M.J.; Phelps, D.K.; Nielson, R.M.; Golovin, M.N.; McManis, G.E. J. Phys. Chem. 1990, 94, 2949.
255. Jimenez, R.; Fleming, G.R.; Kumar, P.V.; MaronceIli, M. Nature 1994, 369, 471.
256. Yoshihara, K.; Tomonaga, K.; Nagasawa, Y. Bull. Chem. Soc. Jpn. 1995, 68, 696.
257. Zusman, L.D. Chem. Phys. 1980, 49, 295.
258. Hynes, J.T. In The Theory of Chemical Reactions; Baer, M., Ed.; CRC Press: Boca Raton, FL, 1985; Vol. 4, p 171.
259. Onuchic, J.N.; Wolynes, P.G. J. Phys. Chem. 1988, 92, 6495.
260. Zichi, D.A.; Cicotti, G.; Hynes, J.T.; Ferrario, M. J. Phys. Chem. 1989, 93, 6211.
261. Bader, J.S.; Kuharski, R.A.; Chandler, D. J. Chem. Phys. 1990, 93, 230.
262. Nelsen, S.F.; Ismagilov, R.F.; Powell, D.R. J. Am. Chem. Soc. 1996, 118, 6313.
263. Nelsen, S.F. J. Am. Chem. Soc. 1996, 118, 2047.
264. Nelson, S.F.; Ramm, M.T.; Wolff, J.J.; Powell, D.R. J. Am. Chem. Soc. 1997, 119, 6863.
265. Meyer, T.J. in Mixed Valence Compounds; Brown, D.M., Ed.; D. Reideh Dordrecht, Holland, 1980; p 75 and references therein.
266. Kauzman, W. Quantum Chemistry: An Introduction; Academic Press: New York, 1957.
267. Crosby, G.A.; Highland, R.G.; Truesdell, K.A. Coord. Chem. Rev. 1985, 64, 41.
268. DeArmond, M.K.; Hanck, K.W.; Wertz, D.W. Coord. Chem. Rev. 1985, 64, 65.
269. Meyer, T.J. Acc. Chem. Res. 1989, 22, 163.
270. Scandola, R.; Indelli, M.T.; Chiorboli, C.; Bignozzi, C.A. Top. Curr. Chem. 1990, 158, 73.
271. Balzani, V.; Scandola, F. Supramolecular Photochemistry; Horwood: Chichester, U.K., 1991; Chapters 5 and 6.
272. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes; Academic Press: London, 1992.
273. (a) Crowley, C.E.; Clark, C.D.; Hoffman, M.Z. Inorg. Chem. 1998, 37, 5704.
274. (b) Li, C.; Hoffman, M.Z. Inorg. Chem. 1998, 37, 830.
275. Kober, E.M.; Sullivan, B.P. Meyer, T. J. Inorg. Chem. 1984, 23, 2098.
276. Oh, D.H.; Boxer, S.G. J. Am. Chem. Soc. 1990, 111, 1130.
277. Dallinger, R.F.; Woodruff, W.H. J. Am. Chem. Soc. 1979, 101, 4391.
278. Bradley, P.G.; Kress, N.; Hornberger, B.A.; Dallinger, R.F.; Woodruff, W.H. J. Am. Chem. Soc. 1981, 103, 7441.
279. Omberg, K.M.; Schoonover, J.R.; Treadway, J.A.; Leasure, R.M.; Dyer, R.B.; Meyer, T.J. J. Am. Chem. Soc. 1997, 119, 7013.
280. 2+, see: Krausz, E.; Ferguson, J. Prog. Inorg. Chem. 1989, 37, 293.
281. Miller, S. J. Inorg. Chem. 1989, 28, 868.
282. Riesen, H.; Wallace, L.; Krausz, E. Int. Rev. Phys. Chem. 1997, 26, 291.
283. Humbs, W.; Strasser, J.; Yersin, H. J. Lumin. 1997, 72-4, 658.
284. Yersin, H.; Humbs, W.; Strasser, J. Coord. Chem. Rev. 1997, 159, 325.
285. Caspar, J.V.; Westmoreland, T.D.; Allen, G.H.; Bradley, P.G.; Meyer, T.J.; Woodruff, W.H. J. Am. Chem. Soc. 1984, 106, 3492.
286. Mabrouk, P.A.; Wrighton, M.S. Inorg. Chem. 1986, 25, 526.
287. Maruszewski, K.; Bajdor, K.; Strommen, D.P.; Kincaid, J.R. J. Phys. Chem. 1995, 99, 6286.
288. The lowest excited "state" is actually a series of three closely spaced, Boltzmann-populated states which share a common dπ-π* MLCT origin and are in rapid equilibrium, see: Hager, G.D.; Crosby, G.A. J. Am. Chem. Soc. 1975, 97, 7031 and Striplin, D.R.; Crosby, G.A. J. Phys. Chem. 1995, 99, 7977.
289. The lowest excited "state" is actually a series of three closely spaced, Boltzmann-populated states which share a common dπ-π* MLCT origin and are in rapid equilibrium, see: Hager, G.D.; Crosby, G.A. J. Am. Chem. Soc. 1975, 97, 7031 and Striplin, D.R.; Crosby, G.A. J. Phys. Chem. 1995, 99, 7977.
290. Cushing, J.P.; Butoi, C.; Kelley, D.F. J. Phys. Chem. A 1997, 101, 7222.
291. Cooley, L.F.; Bergquist, P.; Kelley, D.F. J. Am. Chem. Sec. 1990, 112, 2612.
292. Malone, R.A.; Kelley, D.F. J. Chem. Phys. 1991, 95, 8970.
293. Pogge, J.L.; Kelley, D.F. Chem. Phys. Lett. 1995, 238, 16.
294. Dattelbaum, D.M.; Meyer, T.J. Submitted for publication.
295. Curtis, J.C.; Bernstein, R.H.; Schmehl, R.H.; Meyer, T. J. Chem. Phys. Lett. 1981, 81, 48.
296. Schanze, K.S.; Neyhart, G.A.; Meyer, T.J. J. Phys. Chem. 1986, 90, 2182.
297. Tapolsky, G.; Duesing, R.; Meyer, T.J. J. Phys. Chem. 1991, 95, 1105.
298. Turner, J.J.; George, M.W.; Johnson, F.P.A.; Westwell, J.R. Coord. Chem. Rev. 1993, 125, 101.
299. Omberg, K.M.; Schoonover, J.R.; Meyer, T.J. J. Phys. Chem. A 1997, 101, 9531.
300. George, M.W.; Johnson, F.P.A.; Turner, J.J.; Westwell, J.R. J. Chem. Soc., Dalton Trans. 1995, 2711.
301. Bignozzi, C.A.; Argazzi, R.; Schoonover, J.R.; Gordon, K.C.; Dyer R.B.; Scandola, F. Inorg. Chem. 1992, 31, 5260.
302. Bignozzi, C.A.; Chiorboli, C.; Scandola, F.; Dyer, R.B.; Schoonover, J.R.; Meyer, T. J. Inorg. Chem. 1994, 33, 1652.
303. Schanze, K.S.; Walters, K.A.; Photoinduced Electron Transfer in Metal-Organic Dyads; Ramamurthy, V., Sehanze, K.S, Eds.; Marcel Dekker: New York, 1998; Vol 2.
304. Sullivan, B.P.; Abruna, H.O.; Finklea, D.J.; Salmon, D.J.; Nagle, J.K.; Meyer, T.J.; Sprintschnik, H. Chem. Phys. Lett. 1978, 58, 389.
305. Mecklenberg, S.L.; Opperman, K.A.; Chon, P.Y.; Meyer, T.J. J. Phys. Chem. 1996, 100, 15145.
306. Chon, P.Y.; Palmer, R.A.; Meyer, T.J. J. Phys. Chem. A 1998, 102, 3042.
307. 1 MLCT state.
308. Claude, J.P.; Williams, D.S.; Meyer, T.J. J. Am. Chem. Soc. 1996, 118, 9782.
309. Claude, J.P.; Omberg, K.M.; Williams, D.S.; Meyer, T.J. Manuscript in preparation.
310. Kober, E.M.; Caspar, J.V.; Lumpkin, R.S.; Meyer, T.J. J. Phys. Chem. 1986, 90, 3722.
311. Freed, K.M.; Jortner, J. J. Chem. Phys. 1970, 52, 6272.
312. Bixon, M.; Jortner, J. J. Chem. Phys. 1968, 48, 715.
313. Englman, R.; Jortner, J. Mol. Phys. 1970, 18, 145.
314. Lin, S, H. Radiationless Transitions; Academic: New York, 1980.
315. Freed, K.F. Top. Curr. Chem. 1972, 31, 65.
316. Lin, S.H. J. Chem. Phys. 1966, 44, 3759.
317. Bixon, M., Jortner, J., Verhoeven, J.W. J. Am. Chem. Soc. 1994, 116, 6, 7349.
318. Closs, G.L.; Calcaterra, L.T.; Green, N.J.; Penfield, K.W. J. Phys. Chem. 1986, 90, 3673.
319. Gould, I.R.; Noukakis, D.; Gomez-Jahn, L.; Young, R.H.; Goodman, J.L.; Farid, S. Chem. Phys. 1993, 176, 439.
320. Gould, I.R.; Young, R.H.; Mueller, L.J.; Albrecht, A.C., Farid, S. J. Am. Chem. Soc. 1994, 116, 8188.
321. Friedman, A.E.; Chambron, J.-C., Sauvage, J.-P.; Turro, N.J.; Barton, J.K. J. Am. Chem. Soc. 1990, 112, 4960.
322. Chen, W.; Turro, C.; Friedman, L.A., Barton, J.K.; Turro, N.J. J. Phys. Chem. B 1997, 101, 6995.
323. Schoonover, J.R.; Bates, W.D.; Meyer, T. J. Inorg. Chem. 1995, 34, 6421.