Toward metal-capped one-dimensional carbon allotropes: Wirelike C6- C20 polyynediyl chains that span two redox-active (η5- C5ME5)Re(NO)(PPh3) endgroups

Journal of the American Chemical Society

Volumn 122, Issue 5, 2000, Pages 810-822

  Dembinski, Roman ^a   Bartik, Tamás ^a   Bartik, Berit ^a   Jaeger, Monika ^a,b   Gladysz, J A ^a,c  

^a UNIVERSITY OF UTAH   (United States)

^b Monika Brady ^*  (United States)

^c UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; RHENIUM COMPLEX;

ARTICLE; CHEMICAL STRUCTURE; CHROMATOGRAPHY; OXIDATION REDUCTION REACTION; RAMAN SPECTROMETRY; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0034624413     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992747z     Document Type: Article

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62. xCu (x = 2, 4, 6) are given in the Supporting Information. (c) Procedures that utilize 1-BuOCu in place of n-BuLi and Cul have also been developed. However, this milder base is not commercially available. These procedures are also given in the Supporting Information, except for one case where there is a distinct yield advantage.
63. xCu (x = 2, 4, 6) are given in the Supporting Information. (c) Procedures that utilize 1-BuOCu in place of n-BuLi and Cul have also been developed. However, this milder base is not commercially available. These procedures are also given in the Supporting Information, except for one case where there is a distinct yield advantage.
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93. 24H).
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101. 3).
102. C≡C fingerprints that facilitate reaction monitoring. This footnote is used to highlight steps where IR monitoring is especially recommended.
103. DSC data for this material are given in Figure 4.
104. IR data for this material are given in Table I.
105. 254, 1:1 v/v hexanes/THF.
106. -1). Italicized values were obtained by Gaussian curve fitting of digitized spectra (PeakFit 4.0, Jandel Scientific; auTofit peaks III deconvolution option with amplitude threshold 3%, width 5.0, and filter 75). These maxima were used in all graphical analyses (Figure 1, inset).
107. 2
108. 2
109. 2
110. 2
111. 2
112. 21a
113. 21a
114. 21a
115. 21a
116. 21a
117. The i-Ph resonance is not observed, or the upfield line of the doublet is obscured by the o-Ph or solvent resonance.
118. Tsuda, T.; Hashimoto, T.; Saegusa, T. J. Am. Chem. Soc. 1972, 94, 658.
119. This compound was added in an inert atmosphere glovebox.
120. This synthesis is based upon methodology reported in the following paper: Hofmeister, H.; Annen, K.; Laurent, H.; Wiechert, R. Angew. Chem. 1984, 96, 720; Angew. Chem., Int. Ed. Engl. 1984, 23, 727.
121. This synthesis is based upon methodology reported in the following paper: Hofmeister, H.; Annen, K.; Laurent, H.; Wiechert, R. Angew. Chem. 1984, 96, 720; Angew. Chem., Int. Ed. Engl. 1984, 23, 727.
122. 3 (R = Me, Et).
123. This synthesis is based upon methodology reported in the following paper: Nishikawa, T.; Shibuya, S.; Hosokawa, S.; Isobe, M. Synlett 1994, 485.
124. 67 20.3 (s).
125. Repeated attempts to obtain correct microanalyses were unsuccessful.