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Volumn 18, Issue 14, 1999, Pages 2619-2627

Bimetallic complexes with conjugated C4, C6, C10, and C14 bridges: Synthetic routes to alkynediyl-bridged bis(carbene) complexes

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EID: 0004685222     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990145i     Document Type: Article
Times cited : (51)

References (72)
  • 13
    • 0003268365 scopus 로고
    • Inorganic and Organometallic Polymers II: Advanced Materials and Intermediates
    • American Chemical Society: Washington, DC
    • (b) Wisian-Neilson, P., Allcock, H. R., Wynne, K. J., Eds. Inorganic and Organometallic Polymers II: Advanced Materials and Intermediates; ACS Symp. Ser. 572; American Chemical Society: Washington, DC, 1994.
    • (1994) ACS Symp. Ser. 572
    • Wisian-Neilson, P.1    Allcock, H.R.2    Wynne, K.J.3
  • 67
    • 0000680667 scopus 로고
    • The aminolysis of the typical Fischer carbene complex with primary amines was studied in detail by kinetic methods, and a fourth-order rate law was observed. The activation entropy is strongly negative, giving rise to a negative Arrhenius activation energy. As a consequence the reaction rate increases with decreasing temperature. See: Werner, H.; Fischer, E. O.; Heckl, B.; Kreiter, C. G. J. Organomet. Chem. 1971, 28, 367.
    • (1971) J. Organomet. Chem. , vol.28 , pp. 367
    • Werner, H.1    Fischer, E.O.2    Heckl, B.3    Kreiter, C.G.4
  • 68
    • 0002128270 scopus 로고
    • 2)Ph]. In the temperature range -60 to -20 °C mixtures of both complexes are obtained. See: (a) Fischer; E. O.; Kalder, H. J. J. Organomet. Chem. 1977, 131, 57.
    • (1977) J. Organomet. Chem. , vol.131 , pp. 57
    • Fischer, E.O.1    Kalder, H.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.