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The analogous coupling reactions with 5, 15-dibromo porphyrin gave lower yields of 2 and 4 (ca. 20-25%) along with more amounts of 23 and 25 (50-60%).
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Since the excitation wavelength corresponds to the high energy edge of the Soret band, inclusion of a rise component with a shorter time constant was reported to lead to better fitting analysis (ref 13a)
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Since the excitation wavelength corresponds to the high energy edge of the Soret band, inclusion of a rise component with a shorter time constant was reported to lead to better fitting analysis (ref 13a).
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The calculation was performed by MOPAC 97 (AM1) on Chem3D Pro (Version 5.0, Cambridge Soft Co.)
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The calculation was performed by MOPAC 97 (AM1) on Chem3D Pro (Version 5.0, Cambridge Soft Co.).
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-
-
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123
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33750217178
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y-transition
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y-transition.
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-
-
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124
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33750221678
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Although we do not have clear explanation for these observations at the present stage, these facts may indicate that the Si-Si energy transfer is accompanied by some photochemical event such as an approach to an equilibrium between the Si-states of the donor and acceptor, as suggested by one of the referees, or formation of delocalized excited state over the donor and acceptor porphyrins
-
Although we do not have clear explanation for these observations at the present stage, these facts may indicate that the Si-Si energy transfer is accompanied by some photochemical event such as an approach to an equilibrium between the Si-states of the donor and acceptor, as suggested by one of the referees, or formation of delocalized excited state over the donor and acceptor porphyrins.
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