Facile regioselective meso-iodination of porphyrins

Tetrahedron Letters

Volumn 39, Issue 51, 1998, Pages 9489-9492

  Nakano, Aiko ^a   Shimidzu, Hitoshi ^a   Osuka, Atsuhiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

Coupling reactions; Energy transfer; Halogenation; Porphyrins and analogues

Indexed keywords

IODINE; PORPHYRIN; PORPHYRIN DERIVATIVE; PYRIDINE; ZINC COMPLEX;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENERGY TRANSFER; HALOGENATION; IODINATION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0032542187     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)02152-2     Document Type: Article

References (9)

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6. [6] Fuhrhop JH. Irreversible reactions on the Porphyrin Periphery (Excuding Oxidations, Reductions, and Photochemical Reactions). In: Dolphin D, Editor. The Porphyrins. Vol. 2. New York: Academic Press. 1978:131-159.
7. 1H-NMR and FAB mass methods.
8. [8] Similar high regioselectivity has been reported for meso-bromination of 5,15-diarylporphyrin with NBS. DiMagno SG, Lin VS, Therien MJ. J. Org. Chem. 1993;58:5983-5993.
9. [9] Lin VS, DiMagno SG, Therien, MJ. Science 1994;264:1105-1111.