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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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0001135635
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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0004120675
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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Frere, P.2
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0344878889
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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0000992211
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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Examples of long π-conjugated monodisperse oligomers of ca. 10 nm molecular length: oligo(p-phenyleneporphyrin), 9-mer, 12 nm: A, Osuka, N. Tanabe, R. P. Zhang, K. Maruyama, Chem. Lett. 1993, 1505; oligo(p-phenylenevinylene), 11-mer, 8nm: U. Stalmach, H. Kolshorn, I. Brehm, H. Meier, Liebigs Ann. 1996, 1449; oligo(p-phenyleneethynylene), 16-mer, 13 nm: L. Jones II, J. S. Schumm, J. M. Tour, J. Org. Chem. 1997, 62, 1388; oligothiophene, 27-mer, 11 nm: H. Nakanishi, N. Sumi, Y. Aso, T. Otsubo, J. Org. Chem. 1998, 63, 8632; oligo(thiophenevinylene), 16-mer, 9.5 nm: I. Jestin, P. Frere, P. Blanchard, J. Roncali, Angew. Chem. 1998, 110, 990; Angew. Chem. Int. Ed. 1998, 37, 942: oligo(thiopheneethynylene), 17-mer, 13 nm: D. L. Pearson, J. M. Tour, J. Org. Chem. 1997, 62, 1376; oligoenediyne, 16-mer, 12 nm: R. E. Martin, T. Mader, F. Diederich, Angew. Chem. 1999, 111, 834; Angew. Chem. Int. Ed. 1999, 38, 817.
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MALDI-TOF-MS measurements were performed on a Shimadzu/ KRATOS KOMPACT MALDI4 spectrometer, using the positive-MALDI-TOF method with a 9-nitroanthracene matrix
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MALDI-TOF-MS measurements were performed on a Shimadzu/ KRATOS KOMPACT MALDI4 spectrometer, using the positive-MALDI-TOF method with a 9-nitroanthracene matrix.
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The ΔE value in Equation (1) represents the energy difference between the allowed (lower) and forbidden (higher) Soret transitions and thus should be double the energy difference between the allowed and unperturbed Soret transitions, which is determined experimentally
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The ΔE value in Equation (1) represents the energy difference between the allowed (lower) and forbidden (higher) Soret transitions and thus should be double the energy difference between the allowed and unperturbed Soret transitions, which is determined experimentally.
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0342278210
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The fluorescence decays of shorter arrays obey a single exponential function but those of longer arrays (Z32, Z64, and Z128) can be fit only with a biexponential function and thus we used the averaged lifetimes
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The fluorescence decays of shorter arrays obey a single exponential function but those of longer arrays (Z32, Z64, and Z128) can be fit only with a biexponential function and thus we used the averaged lifetimes.
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[12]
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[12]
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