Synthesis and electronic properties of d8 transition-metal complexes of vinylene-bridged bis- and tris(octaethyiporphyrin)s

Bulletin of the Chemical Society of Japan

Volumn 72, Issue 8, 1999, Pages 1887-1898

  Higuchi, Hiroyuki ^a   Shinbo, Masatoshi ^a   Usuki, Masanobu ^a   Takeuchi, Makoto ^a   Hasegawa, Yutaka ^a   Tani, Keita ^b   Ojima, Juro ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

^b OSAKA KYOIKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

METAL; NICKEL; PALLADIUM; PLATINUM; PORPHYRIN DERIVATIVE; VINYL DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; CONFORMATION; ISOMER; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 0032809998     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.72.1887     Document Type: Article

References (35)

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35. Some mixted metal complexes describedas tris(OEP)-(M1-M2-M3) have been already synthesized as well. A part of physical properties of the tris(OEP)-(Ni-Pd-Pt) complex, of which three constituent OEP rings carry Ni(II), Pd(II), and Pt(II) ions in order of atomic number, has been preliminarily reported: M. Takeuchi, M. Shinbo, Y. Hasegawa, H. Higuchi, and J. Ojima, "The 74th National Meeting of Chemical Society of Japan," Kyoto, Abstr., No. 1 D3 10, p. 890 (1998). Experimental results for the structural properties of the oxidation products from not only the title complexes but also these mixed ones will be reported elsewhere.