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13
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2442737326
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note
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The small blue shifts in the optical bands are consistent with the removal of one non-hydrogen meso substituent and the addition of one non-hydrogen β-pyrrole substituent in the β-versus meso-substituted compounds (compare Figures 1 and 2). The extreme example of such changes is that the absorption spectra of complexes bearing only β-pyrrole substituents such as Fb octaethylporphyrin are blue-shifted from complexes containing only meso substituents such as Fb tetraphenylporphyrin or its tetraalkylporphyrin analogues.
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14
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0006854226
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15
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2442758927
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note
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The Zn* Q(0,0) stimulated emission in ZnFbU-β occurs at essentially the same wavelength as the Q(0,0) spontaneous emission observed near 585 nm for ZnU-β (Figure 5C), and this emission in turn is only slightly red-shifted from the Q(0,0) ground-state absorption band (Figure 3C).
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16
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2442756692
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note
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y(0,0) ground-state absorption band is diminished in the Fb porphyrins in which a β substituent replaces one meso substituent (e.g., FbU-β in Figures 1 and 3) relative to the strictly meso-substituted complexes (e.g., FbU in Figures 2 and 4).
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17
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2442732128
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note
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4,6,12
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18
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2442767263
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note
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30ZnFbU-β.
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19
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0028549485
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Seth, J.; Palaniappan, V.; Johnson, T. E.; Prathapan, S.; Lindsey, J. S.; Bocian, D. F. J. Am. Chem. Soc. 1994, 116, 10578-10592.
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0002092712
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Dolphin, D., Ed.; Academic Press: New York
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Felton, R.H.1
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0001342120
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Dolphin, D., Ed.; Academic Press: New York
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