Exceptional electronic modulation of porphyrins through meso-arylethynyl groups. Electronic spectroscopy, electronic structure, and electrochemistry of [5,15-bis](aryl)ethynyl]-10,20-diphenylporphinato]zinc(II) complexes

Journal of the American Chemical Society

Volumn 118, Issue 47, 1996, Pages 11854-11864

  LeCours, Steven M ^a   DiMagno, Stephen G ^a,b   Therien, Michael J ^a  

^a UNIVERSITY OF PENNSYLVANIA   (United States)

^b UNIVERSITY OF NEBRASKA LINCOLN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PORPHYRIN DERIVATIVE;

ARTICLE; DRUG STRUCTURE; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE;

EID: 0029902288     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962403y     Document Type: Article

References (56)

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27. 2) shows the following: (5,10,15,20-tetraphenylporphinato)Ni(II) (λ = 414 nm); (5,10,15,20-tetraphenyl-2,3,7,8,12,13,17,18-octamethylporphinato)Ni(II)(λ = 418 nm); (5,10,15,20-tetraperfluorophenyl-2,3,7,8,12,13,17,1-octabromoporphinato)Ni(II) (λ = 436 nm); (5.10,15,20-tetraphenyl-2,3,7,8,12, 13,17,18-octabromoporphinato)Ni(II) (λ = 448 nm); (2,3,5,7,8,10,12,13, 15,17,18,20-dodecaphenylporphinato)Ni(II) (λ = 448 nm). See refs 5b. e, f, and g.
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44. 2) reported in this study analyze as their axialligand free derivatives (see Experimental Section). In general, if dried under vacuum for 24 h at 120°C, these compounds are isolated free of axial THF ligands; if simply recrystallized from THF, they are isolated as their bis(THF) adducts.
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48. 21
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