Mechanistic insight into ketone α-alkylation with unactivated olefins via C-H activation promoted by metal-organic cooperative catalysis (MOCC): Enriching the MOCC chemistry

Journal of the American Chemical Society

Volumn 137, Issue 19, 2015, Pages 6279-6291

  Dang, Yanfeng ^a   Qu, Shuanglin ^a   Tao, Yuan ^a   Deng, Xi ^a   Wang, Zhi Xiang ^a,b  

^a UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^b SynBio Research Platform   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; ALKYLATION; CATALYSIS; CATALYSTS; CHEMICAL ACTIVATION; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; KETONES; OLEFINS; ORGANOMETALLICS; REDOX REACTIONS; RHODIUM;

AGOSTIC INTERACTIONS; COOPERATIVE CATALYSIS; DENSITY FUNCTIONAL THEORY STUDIES; MIGRATORY INSERTION; OXIDATIVE ADDITIONS; RATE DETERMINING STEP; REDUCTIVE ELIMINATION; WILKINSON'S CATALYST;

IODINE;

ALKENE; ENAMINE; KETONE; METAL ORGANIC FRAMEWORK;

ALKYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELIMINATION REACTION; ENERGY; HYDROGEN BOND; HYDROLYSIS; STEREOCHEMISTRY;

EID: 84930206839     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b01502     Document Type: Article

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