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Volumn 110, Issue 4, 2010, Pages 2366-2447

Addition of metal enolate derivatives to unactivated carbon-carbon multiple bonds

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; METALS; NUCLEOPHILES; OLEFINS; PALLADIUM COMPOUNDS;

EID: 77951228078     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/cr800420x     Document Type: Article
Times cited : (247)

References (489)
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    • The use of HMPA has been found to increase the yields obtained with stabilized anion. In these conditions, ketone and ester enolates, as well as oxazoline and protected cyanhydrin anions, add onto alkenes in moderate to good yields; see ref 43
    • The use of HMPA has been found to increase the yields obtained with stabilized anion. In these conditions, ketone and ester enolates, as well as oxazoline and protected cyanhydrin anions, add onto alkenes in moderate to good yields; see ref 43.
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    • The formation of Pd-hydride was previously demonstrated by Trost for the formation of dimeric enynes from terminal alkynes
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    • A similar rearrangement involving Rh-carbene species has been reported:, and references cited therein
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    • For related examples of carbometalation reactions onto metalated alkynes, see ref 8b and references cited therein.
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    • This reaction has been previously observed with 1-iodo-phenylacetylene
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.