Hydroacylation of 1-alkene with heteroaromatic aldehyde by Rh(I) and additives

Tetrahedron Letters

Volumn 38, Issue 38, 1997, Pages 6673-6676

  Jun, Chul Ho ^a   Lee, Dae Yon ^a   Hong, Jun Bae ^a  

^a Yonsei University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; ALKENE; FURFURAL;

ACYLATION; ARTICLE; CHELATION; CHEMICAL MODIFICATION; CHEMICAL REACTION; REACTION ANALYSIS;

EID: 0030864563     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01562-1     Document Type: Article

References (24)

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21. 2, and ferrocene were examined, but they did not show any improvement in the catalytic activity for hydroacylation.
22. When catalytic amount(20 mol%) of 4 was used, the yields decreased; only 17 % yield of 5h was obtained for 1h with 10 mol% of 14.
23. For 1h, when the reaction was carried out without additive, white precipitate, hardly characterized, was formed, possibly indicating the formation of the intermolecular complexes.
24. 2, 166.099 380, found 166.099 648.