Dimer involvement and origin of crossover in nickel-catalyzed aldehyde-alkyne reductive couplings

Journal of the American Chemical Society

Volumn 136, Issue 50, 2014, Pages 17495-17504

  Haynes, M Taylor ^a   Liu, Peng ^b,c   Baxter, Ryan D ^a,d   Nett, Alex J ^a   Houk, K N ^b   Montgomery, John ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c UNIVERSITY OF PITTSBURGH   (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; CATALYSIS; LIGANDS; NICKEL; PHOSPHORUS COMPOUNDS;

COMPUTATIONAL EVALUATION; METALLACYCLES; METALLACYCLIC INTERMEDIATES; N-HETEROCYCLIC CARBENES; REDUCTIVE COUPLINGS; RING SIZES; STERICS;

HYDROCARBONS;

ALDEHYDE; ALKYNE; CARBENE; DIMER; NICKEL; PHOSPHINE; LIGAND; SILANE DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; COMPUTER ANALYSIS; CROSS COUPLING REACTION; CYCLIZATION; DIMERIZATION; DISSOCIATION; TEMPERATURE; THERMODYNAMICS; CHEMICAL STRUCTURE; CHEMISTRY; COMPUTER SIMULATION; OXIDATION REDUCTION REACTION;

ALDEHYDES; ALKYNES; CATALYSIS; COMPUTER SIMULATION; DIMERIZATION; LIGANDS; MOLECULAR STRUCTURE; NICKEL; OXIDATION-REDUCTION; SILANES;

EID: 84919346978     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja508909u     Document Type: Article

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