A computational mechanistic study of an unprecedented heck-type relay reaction: Insight into the origins of regio- and enantioselectivities

Journal of the American Chemical Society

Volumn 136, Issue 3, 2014, Pages 986-998

  Dang, Yanfeng ^a   Qu, Shuanglin ^a   Wang, Zhi Xiang ^a,c   Wang, Xiaotai ^b  

^a UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^b UNIVERSITY OF COLORADO   (United States)

^c Collaborative Innovation Center of Chemical Science and Engineering   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL FUNCTIONALITY; DISPERSION INTERACTION; ELECTRONIC EFFECTS; HYDRIDE ELIMINATION; INITIAL OXIDATION; MECHANISTIC STUDIES; MIGRATORY INSERTION; STERIC REPULSIONS;

AROMATIC COMPOUNDS; CARBON; ORGANIC POLYMERS; PALLADIUM COMPOUNDS; SUBSTITUTION REACTIONS;

ENANTIOSELECTIVITY;

ALCOHOL; BENZOPHENONE; CARBON; CARBONYL DERIVATIVE; HYDROGEN; HYDROXYL GROUP; KETONE; PALLADIUM; PALLADIUM COMPLEX; PHENYL GROUP; PYRIDINE;

ARTICLE; ARYLATION; CHEMICAL BOND; CHEMICAL REACTION KINETICS; DENSITY FUNCTIONAL THEORY; DIASTEREOISOMER; DISPERSION; DISSOCIATION; ENANTIOSELECTIVITY; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REGIOSELECTIVITY; STATIC ELECTRICITY; STEREOCHEMISTRY;

EID: 84893023130     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja410118m     Document Type: Article

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