Selective catalytic deuterium labeling of alcohols during a transfer hydrogenation process of ketones using D2O as the only deuterium source. Theoretical and Experimental demonstration of a Ru-H/D+ exchange as the key step

ACS Catalysis

Volumn 4, Issue 4, 2014, Pages 1040-1053

  Carrión, M Carmen ^a,b   Ruiz Castaneda, Margarita ^a   Espino, Gustavo ^c   Aliende, Cristina ^c   Santos, Lucía ^d   Rodríguez, Ana M ^e   Manzano, Blanca R ^a   Jalón, Félix A ^a   Lledós, Agustí ^f  

^a Facultad de Ciencias y Tecnologías Químicas IRICA   (Spain)

^b Renewable Energy Research Institute   (Spain)

^c UNIVERSITY OF BURGOS   (Spain)

^d Analytical Chemistry and Food Science Dept   (Spain)

^e ETS Ingenieros Industrials   (Spain)

^f UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

catalysis in water; density functional calculations; deuterium labeling; hydrogen transfer; ruthenium; umpolung

Indexed keywords

CATALYSIS IN WATER; CATALYTIC TRANSFER HYDROGENATION; DEUTERIUM LABELING; EXPERIMENTAL DEMONSTRATIONS; HYDROGEN TRANSFER; MICROSCOPIC DESCRIPTION; TRANSFER HYDROGENATIONS; UMPOLUNG;

CARBOXYLATION; CATALYSIS; DENSITY FUNCTIONAL THEORY; HYDROGEN; HYDROGENATION; KETONES; NITROGEN COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; RUTHENIUM;

DEUTERIUM;

EID: 84898079845     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs401224g     Document Type: Article

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