Isolation and crystal structure of a water-soluble iridium hydride: A robust and highly active catalyst for acid-catalyzed transfer hydrogenations of carbonyl compounds in acidic media

Journal of the American Chemical Society

Volumn 125, Issue 14, 2003, Pages 4149-4154

  Abura, Tsutomu ^a,b   Ogo, Seiji ^a   Watanabe, Yoshihito ^c   Fukuzumi, Shunichi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b GRADUATE UNIVERSITY FOR ADVANCED STUDIES   (Japan)

^c NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COMPLEXATION; CRYSTAL STRUCTURE; SOLUBILITY; WATER;

ACTIVE CATALYSTS;

IRIDIUM COMPOUNDS;

CARBONYL DERIVATIVE; IRIDIUM;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; COMPLEX FORMATION; CRYSTAL STRUCTURE; DRUG ISOLATION; HYDROGENATION; LIGAND BINDING; PROTON TRANSPORT; STOICHIOMETRY; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE; X RAY ANALYSIS;

EID: 0037427321     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0288237     Document Type: Article

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34. Conditions: 2/carbonyl compounds/HCOOH = 1/200/1000, pH 2.0, 70 °C.
35. 2.
36. Conditions: Ru catalyst/b/HCOONa = 1/200/6000, pH 4.0, 70 °C.