Accelerating Effect of a Proton on the Reduction of CO2 Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex

Journal of the American Chemical Society

Volumn 125, Issue 47, 2003, Pages 14266-14267

  Hayashi, Hideki ^a   Ogo, Seiji ^a   Abura, Tsutomu ^a   Fukuzumi, Shunichi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; PROTON; RUTHENIUM COMPLEX;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CRYSTAL STRUCTURE; HYDROGENATION; REDUCTION;

EID: 0344443380     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036117f     Document Type: Article

References (27)

1. Reviews: (a) Joó, F. Catalysis by Metal Complexes; Kluwer Academic Publishers: Dordrecht, The Netherlands, 2001; Vol. 23, Aqueous Organometallic Catalysis, pp 113-122 and references therein.
2. (b) Leitner, W.; Dinjus, E.; Gassner, F. In Aqueous-Phase Organometallic Catalysis, Concepts and Applications; Cornils, B., Herrmann, W. A., Eds.; Wiley-VCH: Weinheim, Germany, 1998; pp 486-498 and references therein.
3. (c) Behr, A. Carbon Dioxide Activation by Metal Complexes; VCH: Weinheim, Germany, 1988, and references therein.
4. - in water at pH 4.0 are about 99.5% and 0.5%, respectively. (a) Lide, D. R. Handbook of Chemistry and Physics, 83rd ed.; CRC Press: Boca Raton, FL, 2002.
5. (b) Cotton, F. A.; Wilkinson, G.; Murillo, C. A.; Bochmann, M. Advanced Inorganic Chemistry, 6th ed.; Wiley-Interscience: New York. 1999; pp 226-227.
6. (a) Joó, F.; Laurenczy, G.; Nádasdi, L.; Elek, J. J. Chem. Soc., Chem. Commun. 1999, 971-972.
7. (b) Laurenczy, G.; Joó, F.; Nádasdi, L. Inorg. Chem. 2000, 39, 5083-5088.
8. (c) Joó, F.; Laurenczy, G.; Karády, P.; Elek, J.; Nádasdi, L.; Roulet, R. Appl. Organomet. Chem. 2000, 14, 857-859.
9. (a) Inoue, Y.; Izumida, H.; Sasaki, Y.; Hashimoto, H. Chem. Lett. 1976, 863-864.
10. (b) Tsai, J.-C.; Nicholas, K. M. J. Am. Chem. Soc. 1992, 114, 5117-5124.
11. (c) Jessop, P. G.; Hsiao, Y.; Ikariya, T.; Noyori, R. J. Am. Chem. Soc. 1996, 118, 344-355.
12. (d) Yin, C.; Xu, Z.; Yang, S.-Y.; Ng, S. M.; Wong, K. Y.; Lin, Z.; Lau, C. P. Organometallics 2001, 20, 1216-1222.
13. (e) Munshi, P.; Main, A. D.; Linehan, J. C.; Tai, C.-C.; Jessop, P. G. J. Am. Chem. Soc. 2002, 124, 7963-7971.
14. Ogo, S.; Abura, T.; Watanabe, Y. Organometallics 2002, 21, 2964-2969.
15. (a) Pu, L. S.; Yamamoto, A.; Ikeda, S. J. Am. Chem. Soc. 1968, 90, 3896.
16. (b) Sullivan, B. P.; Meyer, T. J. Organometallics 1986, 5, 1500-1502.
17. (c) Darensbourg, D. J.; Wiegreffe, H. P.; Wiegreffe, P. W. J. Am. Chem. Soc. 1990, 112, 9252-9257.
18. (d) Whittlesey, M. K.; Perutz, R. N.; Moore, M. H. Organometallics 1996, 15, 5166-5169.
19. (e) McLoughlin, M. A.; Keder, N. L.; Harrison, W. T. A.; Flesher, R. J.; Mayer, H. A.; Kaska, W. C. Inorg. Chem. 1999, 38, 3223-3227.
20. (f) Yin, X.; Moss, J. R. Coord. Chem. Rev. 1999, 181, 27-59.
21. (g) Konno, H.; Kobayashi, A.; Sakamoto, K.; Fagalde, F.; Katz, N. E.; Saitoh, H.; Ishitani, O. Inorg. Chim. Acta 2000, 299, 155-163.
22. (h) Field, L. D.; Lawrenz, E. T.; Shaw, W. J.; Turner, P. Inorg. Chem. 2000, 39, 5632-5638.
23. 3) have been deposited with the Cambridge Crystallographic Data Center as supplementary publication No. CCDC-210229.
24. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; Wiley: New York, 1997.
25. 2- may be the actual substrate for the reduction by 1.
26. 2) intermediate.
27. Cheng, T.-Y.; Bullock, R. M. J. Am. Chem. Soc. 1999, 121, 3150-3155.