Highly efficient redox isomerisation of allylic alcohols catalysed by pyrazole-based ruthenium(IV) complexes in Water: Mechanisms of bifunctional catalysis in water

Chemistry - A European Journal

Volumn 18, Issue 25, 2012, Pages 7749-7765

  Bellarosa, Luca ^b   Díez, Josefina ^a   Gimeno, Joś ^a   Lledós, Agustí ^b   Suárez, Francisco J ^a   Ujaque, Gregori ^b   Vicent, Cristian ^c  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^c UNIVERSITAT JAUME I   (Spain)

Author keywords

Allylic alcohols; Cooperating ligands; Isomerisation; Ruthenium water chemistry

Indexed keywords

ACTIVE SPECIES; ALLYLIC ALCOHOL; AQUA COMPLEXES; AQUEOUS MEDIUM; AQUEOUS SPECIES; BI-FUNCTIONAL CATALYSTS; BIFUNCTIONAL; BIFUNCTIONAL CATALYSIS; CATALYTIC PROCESS; CONTINUUM MODEL; DEPROTONATED SPECIES; DFT CALCULATION; EXPLICIT WATER; INDAZOLE; ISOMERISATION; NEW MECHANISMS; P-CYMENE; PYRAZOLES; ROLE OF WATER; RUTHENIUM COMPLEXES; TURNOVER FREQUENCY; WATER CHEMISTRY;

CATALYSIS; CATALYST ACTIVITY; CHLORINE COMPOUNDS; CONTINUUM MECHANICS; DENSITY FUNCTIONAL THEORY; HYDROGEN; ISOMERIZATION; LIGANDS; OLEFINS; PHENOLS; RUTHENIUM; SPHERES;

RUTHENIUM COMPOUNDS;

EID: 84862634364     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201103374     Document Type: Article

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