Anion-exchange-triggered 1,3-Shift of an NH proton to iridium in protic N-heterocyclic carbenes: Hydrogen-bonding and Ion-pairing effects

Angewandte Chemie - International Edition

Volumn 49, Issue 5, 2010, Pages 912-917

  Song, Guoyong ^b   Su, Yan ^a   Periana, Roy A ^b   Crabtree, Robert H ^c   Han, Keli ^a   Zhang, Hongjie ^d   Li, Xingwei ^b  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b SCRIPPS RESEARCH INSTITUTE   (United States)

^c YALE UNIVERSITY   (United States)

^d CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ANION EXCHANGE; COORDINATING ANIONS; HYDROGEN BONDINGS; ION-PAIRING; N-HETEROCYCLIC CARBENE LIGANDS; N-HETEROCYCLIC CARBENES; PHOSPHINE COMPLEX; PROTON RELEASE;

CARBON INORGANIC COMPOUNDS; CHLORINE COMPOUNDS; HYDROGEN BONDS; ION EXCHANGE; IRIDIUM; LIGANDS; NEGATIVE IONS; PHOSPHORUS COMPOUNDS; PROTONS;

IRIDIUM COMPOUNDS;

ANION; CARBENE; DRUG DERIVATIVE; HETEROCYCLIC COMPOUND; IRIDIUM; METHANE; PROTON; WATER;

ARTICLE; CHEMISTRY; CONFORMATION; HYDROGEN BOND; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

ANIONS; CRYSTALLOGRAPHY, X-RAY; HETEROCYCLIC COMPOUNDS; HYDROGEN BONDING; IRIDIUM; METHANE; MOLECULAR CONFORMATION; PROTONS; THERMODYNAMICS; WATER;

EID: 75749157028     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.200905691     Document Type: Article

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