Rh-catalyzed C-C cleavage of benzyl/allylic alcohols to produce benzyl/allylic amines or other alcohols by nucleophilic addition of intermediate rhodacycles to aldehydes and imines

Chemistry - A European Journal

Volumn 18, Issue 50, 2012, Pages 16214-16225

  Zhang, Xi Sha ^a   Li, Yang ^a   Li, Hu ^a   Chen, Kang ^a   Lei, Zhi Quan ^a,c   Shi, Zhang Jie ^a,b  

^a PEKING UNIVERSITY   (China)

^b INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

^c CHENGDU INSTITUTE OF BIOLOGY   (China)

Author keywords

alcohols; allylic compounds; C C activation; rhodium; synthetic methods

Indexed keywords

ALCOHOL GROUP; ALKENYL; ALLYLIC ALCOHOL; ALLYLIC AMINES; ALLYLIC COMPOUNDS; C-C ACTIVATIONS; C-C BONDS; CARBON SKELETON; DOUBLE BONDS; DRIVING FORCES; ELECTRON-DEFICIENT; ELECTRON-RICH; IN-DEPTH INVESTIGATION; ISOTOPIC LABELING; LEAVING GROUPS; MECHANISTIC STUDIES; NUCLEOPHILIC ADDITIONS; PROTONATED; PYRAZOLYL; PYRIDYL GROUPS; REACTION CONDITIONS; SECONDARY ALCOHOLS; SIGNIFICANT IMPACTS; SPECTROSCOPIC STUDIES; SYNTHETIC METHODS;

ADDITION REACTIONS; ALCOHOLS; ALDEHYDES; AMINES; CATALYSIS; COVALENT BONDS; RHODIUM; RHODIUM COMPOUNDS; SPECTROSCOPIC ANALYSIS;

REACTION INTERMEDIATES;

ALCOHOL DERIVATIVE; ALDEHYDE; ALLYL ALCOHOL; AMINE; BENZYL DERIVATIVE; PROPANOL; RHODIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HYDROGENATION; STEREOISOMERISM;

ALCOHOLS; ALDEHYDES; AMINES; BENZYL COMPOUNDS; CATALYSIS; HYDROGENATION; MOLECULAR STRUCTURE; PROPANOLS; RHODIUM; STEREOISOMERISM;

EID: 84870616648     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201201867     Document Type: Article

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