Beyond thermodynamic acidity: A perspective on the complex-induced proximity effect (CIPE) in deprotonation reactions

Angewandte Chemie - International Edition

Volumn 43, Issue 17, 2004, Pages 2206-2225

  Whisler, Marna C ^b   MacNeil, Stephen ^c   Snieckus, Victor ^d   Beak, Peter ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

^b JOHNSON AND JOHNSON PHARMACEUTICAL RESEARCH AND DEVELOPMENT   (United States)

^c WILFRID LAURIER UNIVERSITY   (Canada)

^d QUEEN S UNIVERSITY   (Canada)

Author keywords

Arenes; Heterocycles; Lithiation; Metalation; Reaction mechanisms

Indexed keywords

DATA ACQUISITION; LITHIUM; SYNTHESIS (CHEMICAL); THERMODYNAMIC PROPERTIES;

CARBANION CHEMISTRY; ORGANOLITHIUM BASES; PROTON-TRANSFER;

STEREOCHEMISTRY;

ALKYL GROUP; ANION; BASE; FUNCTIONAL GROUP; ISOTOPE; NATURAL PRODUCT; ORGANOLITHIUM COMPOUND; REAGENT; VINYL DERIVATIVE;

ACIDITY; CALCULATION; CHEMICAL REACTION; COMPLEX FORMATION; INFRARED SPECTROSCOPY; ISOTOPE LABELING; KINETICS; LITHIATION; ORGANIC CHEMISTRY; PROTON TRANSPORT; REACTION ANALYSIS; REVIEW; STEREOCHEMISTRY; SYNTHESIS; THERMODYNAMICS;

EID: 3242659209     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200300590     Document Type: Review

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