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Volumn 20, Issue 13, 2001, Pages 2928-2931

Catalytic carbon-carbon bond activation of sec-Alcohols by a Rhodium(I) complex

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CARBON; CHEMICAL BONDS; HYDROGENATION; KETONES; OLEFINS; OXIDATION;

EID: 0035948514     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010087c     Document Type: Article
Times cited : (55)

References (60)
  • 1
    • 0002583629 scopus 로고    scopus 로고
    • Murai, S., Ed.; Topics in Organometallic Chemistry 3; Springer: Berlin, Germany
    • (a) Murakami, M.; Ito, Y. In Topics in Organometallic Chemistry; Murai, S., Ed.; Topics in Organometallic Chemistry 3; Springer: Berlin, Germany, 1999; pp 97-129.
    • (1999) Topics in Organometallic Chemistry , pp. 97-129
    • Murakami, M.1    Ito, Y.2
  • 42
    • 0011504198 scopus 로고    scopus 로고
    • note
    • In the case of ruthenium-catalyzed hydrogen transfer, chlorides in the ruthenium complex are removed to give active species in the presence of base. We anticipate that this type of removal of chloride deteriorates the rhodium catalyst in the C-C bond activation.
  • 43
    • 0011504199 scopus 로고    scopus 로고
    • note
    • This type of skeletal rearrangement was identified by the fact that 5a was heated with 3 and 4 without alkene to afford 10 in 7% yield. Similarly, 10 was also isomerized to 5a under the same reaction conditions to give a mixture of 5a and 10 in a ratio of 11:89.
  • 45
    • 0001194811 scopus 로고
    • Imine is thought to be an intermediate in ruthenium-catalyzed N-alkylation of amine by alcohol: (a) Watanabe, Y.; Tsuji, Y.; Ohsugi, Y. Tetrahedron Lett. 1981, 22, 2667.
    • (1981) Tetrahedron Lett. , vol.22 , pp. 2667
    • Watanabe, Y.1    Tsuji, Y.2    Ohsugi, Y.3
  • 48
    • 0035977634 scopus 로고    scopus 로고
    • note
    • 3P, which had been used in the reaction of cycloalkanone imine, was not effective in the reaction of alcohol because this catalyst system was inactive in the hydrogen transfer reaction.
    • (2001) J. Am. Chem. Soc. , vol.123 , pp. 751
    • Jun, C.-H.1    Lee, H.2    Lim, S.-G.3
  • 49
    • 0011511361 scopus 로고    scopus 로고
    • note
    • In cases of small-ring cycloalkanols such as 16a and 16b, skeletal rearrangement products such as 2-methylcyclopentanone (1%, from 16a), 2-methylcyclohexanone (8%, from 16b), and 2-ethylcyclopentanone (4%, from 16b) were obtained.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.